The physical, mechanical, thermal and barrier properties of starch nanoparticle (SNP)/polyurethane (PU) nanocomposite films synthesised by an ultrasound-assisted process

Hakke, Vikas S.; Landge, Vividha K.; Sonawane, Shirish H.; Babu, G. Uday Bhaskar; Ashokkumar, Muthupandian; Flores, Érico M.M.

doi:10.1016/j.ultsonch.2022.106069

Cited by 18 publications

(12 citation statements)

References 51 publications

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“…Film thickness is an important parameter that a ects its application as a material for product packaging. It also a ects other parameters, such as transparency, tensile strength, and the transparency rate of steam or gas on the material (González et al, 2015;Gujral et al, 2021;Hakke et al, 2022;Totosaus et al, 2020). The results showed that increasing the concentration of modi ed cassava starch signi cantly increased the thickness of the edible lm (p<5%), as shown in Table 2.…”

Section: The Characteristics Of the Edible Film With The Addition Of ...mentioning

confidence: 93%

Improving the Characteristics of Edible Film Using Modified Cassava Starch Over Ethanol Precipitation

Nazarudin¹,

Ulyarti

Pratama

et al. 2023

Sci. Technol. Indones

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Cassava starch has been widely explored as film forming material, however its hydrophilicity restricts its application. Hydrophobic material such as modified starch can be used in the film elaboration to improve its quality. This study aims to examine the effect of modified cassava starch concentration on the physical, barrier, and mechanical properties of edible films. A completely randomized design was used with 5 concentrations of modified starch at 0%, 5%, 10%, 15%, and 20% and 4 repetitions to obtain a total of 20 experimental combinations. The ANOVA showed that the modified starch concentration affected the compressive strength, thickness, transparency, and solubility of the edible film, but has no effect on its water vapor transmission rate (WVTR). Usage of 20% modified starch gave the product with the best characteristics at 0.22 mm thickness, 89.45 N/m2 strength, 6.484%/mm transparency, 52.19% solubility, and 21.00 g/m2.hour WVTR.

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Section: The Characteristics Of the Edible Film With The Addition Of ...mentioning

confidence: 93%

Improving the Characteristics of Edible Film Using Modified Cassava Starch Over Ethanol Precipitation

Nazarudin¹,

Ulyarti

Pratama

et al. 2023

Sci. Technol. Indones

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“…WVP: The WVP of ultrasonically treated pristine WPU and ZIF-8/WPU nanocomposites was analyzed based on the previous method with some modifications. [51] Typically in 10 mL of a glass beaker, 5 mL of DI water was added and sealed with the synthesized films (area %4.9 cm 2 ) and allowed in desiccator followed by 7 days of observation at room temperature. The anhydrous calcium chloride was placed in the desiccator to maintain the film's relative humidity (RH).…”

Section: Methodsmentioning

confidence: 99%

Sonochemical Approach of Highly Thermal, Mechanical, and Corrosion Inhibition Performance of Metal–Organic Framework (ZIF‐8)‐Decorated Waterborne Polyurethane Nanocomposite

et al. 2023

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Herein, highly porous metal-organic framework (ZIF-8)-decorated environmental friendly waterborne polyurethane (WPU) (ZIF-8@WPU) nanocomposites via facile sonochemical technique are synthesized. The ZIF-8@WPU shows threefold excellent mechanical performance (tensile strength %23 MPa and elongation 670%) at a very low 2.5 wt% filler loading compared to pristine WPU. In addition, the synthesized ZIF-8@WPU exhibits high thermal stability and water vapor permeability properties with increasing nanofiller concentration. Interestingly, the incorporation of ZIF-8 into WPU potentially improves the corrosion inhibition performance with a superior corrosion rate ( υ corr) 1.7 Â 10 À2 mm year À1 and %94% protection efficiency (PE) at lower filler (2.5 wt%) loading, attributing to the facile synthesis methods, internal structural arrangement, well interaction of filler and matrix, high surface area, and tuneable pore size of filler material. The crystallinity of ZIF-8 and ZIF-8@WPU is analyzed by powder X-ray diffraction, morphology by scanning electron microscopy, thermal properties by thermogravimetric analysis, and mechanical properties by the universal testing machine. This new insight has potential toward the green approach for synthesizing and structural engineering high-performance advanced nanocomposites in the coating, breathable devices, and food packaging industrial utilization.

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“…Water-Vapor Permeability (WVP) Performance of Nanocomposite Films: The water vapor permeability of ultrasonically treated pristine WPU and Ni-ZIF-67/WPU nanocomposites were analyzed based on the previous method with some modifications. [42] Typically in 10 mL of a glass beaker, 5 mL of DI water was added and sealed with the synthesized films (area ≈4.9 cm 2 ) and allowed in a desiccator followed by 7 days of observation at room temperature. The anhydrous calcium chloride was placed in the desiccator to maintain the film's relative humidity (RH).…”

Section: Mechanical Properties Of Nanocompositementioning

confidence: 99%

Synthesis and Characterization of Multifunctional Metal‐Organic Framework (Ni‐ZIF‐67) Decorated Waterborne Polyurethane (Ni‐ZIF‐67/WPU) Nanocomposites: Sonochemical Approach

Borse

Kale

Hakke

et al. 2022

Adv Materials Inter

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This work investigates the effect of a modified nickel‐doped metal‐organic framework (Ni‐ZIF‐67) as a filler on thermal, mechanical, and water vapor permeability properties of environmentally friendly waterborne polyurethane (WPU). The facile and greener ultrasound (sonochemical) technique is developed to prepare multifunctional Ni‐ZIF‐67@WPU nanocomposites, exhibiting superior crystallinity and uniform distribution. The resultant Ni‐ZIF‐67 nanoparticles and Ni‐ZIF‐67@WPU films are characterized by various techniques, including powder XRD, FE‐SEM, FTIR, TGA, UTM, contact angle, and antibacterial properties. Ni‐ZIF‐67@WPU nanocomposites exhibited excellent three‐fold mechanical performance (tensile strength ≈22 MPa) at a very low 5 wt.% filler loading and high thermal stability compared to pristine WPU. In addition, Ni‐ZIF‐67@WPU exhibited optimum water vapor permeability performance at 5.0 wt.% filler with the potential antibacterial application. Demonstrate that the rapid and facile synthesis approach can enhance the interaction of filler and matrix, high surface area, and tuneable pore size of filler material. This new insight has a new green approach for fabricating advanced nanocomposites toward practical utilization.

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The physical, mechanical, thermal and barrier properties of starch nanoparticle (SNP)/polyurethane (PU) nanocomposite films synthesised by an ultrasound-assisted process

Cited by 18 publications

References 51 publications

Improving the Characteristics of Edible Film Using Modified Cassava Starch Over Ethanol Precipitation

Improving the Characteristics of Edible Film Using Modified Cassava Starch Over Ethanol Precipitation

Sonochemical Approach of Highly Thermal, Mechanical, and Corrosion Inhibition Performance of Metal–Organic Framework (ZIF‐8)‐Decorated Waterborne Polyurethane Nanocomposite

Synthesis and Characterization of Multifunctional Metal‐Organic Framework (Ni‐ZIF‐67) Decorated Waterborne Polyurethane (Ni‐ZIF‐67/WPU) Nanocomposites: Sonochemical Approach

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