To
determine the main factors controlling hydrogen sulfide enrichment
in coal mines, the #4 coal seam in the Binchang Xiaozhuang coal mine,
China, was investigated. A new hydrogen sulfide control method was
also tested on this seam. Using coal petrography, X-ray diffraction,
and other techniques, the reactions that generated hydrogen sulfide
in the Xiaozhuang coal were investigated. The main controlling factors
that affect the physical and chemical properties of coal and its H2S are analyzed from the perspectives of thermal evolution
temperature, gas adsorption, pore characteristics, total sulfur content,
and the coal’s reducibility index. In addition, the degree
of correlation for each factor was determined quantitatively using
the gray system theory to construct a generalized gray relational
degree evaluation model. Finally, a high-pressure circulating pulsed
alkali treatment technique was proposed to cope with the dangerous
levels of hydrogen sulfide found in coal mines. The treatment technique
was applied in the field. The results of the investigation on hydrogen
sulfide formation show that H2S in the #4 coal seam was
generated by biological sulfate reduction. When the concentration
of hydrogen sulfide increased from 0.8 to 6 ppm, the ranges of the
thermal evolution temperature, the adsorption constant, the Brunauer–Emmett–Teller
(BET) specific surface area, the total sulfur content, and the reducibility
index increased from 96 to 113 °C, 28.8 to 36.2, 0.4125 to 0.9864
m2·g–1, 0.21 to 0.88%, and 3.1 to
8.5, respectively. The correlation coefficients of the main controlling
factors, in a descending order, were as follows: reducibility index
> adsorption constant > total sulfur content > thermal evolution
temperature
> BET specific surface area. The high-pressure circulating pulsed
alkali treatment method tested can effectively control the high concentrations
of hydrogen sulfide and prevent hydrogen sulfide-related mine shutdowns.