States often fight side-by-side on the battlefield. As detailed in our new dataset, Belligerents in Battle, 178 of the 480 major land battles fought during interstate wars waged between 1900 and 2003 involved at least one multinational coalition. Though coalition partners fight battles together to increase their odds of securing specific objectives, they vary significantly in their capacity to do so. Why? Drawing on organization theory insights, we argue that coalitions’ variable battlefield effectiveness is a function of interactions between their command structures and the resources each partner brings to the fight. Coalitions adopting command structures tailored to simultaneously facilitate the efficient use of partners’ variably sized resource contributions and discourage free-riding, shirking, and other counterproductive actions will fight effectively; those that employ inappropriate command structures will not. Evidence from Anglo-French operations during World War I and Axis operations during World War II strongly supports our claim. For scholars, our argument and findings about the importance of military organizational dynamics for the operation and performance of coalitions raise important new questions and provide potential insights about coalition formation, duration, and termination. For practitioners, it is significant that, since 1990, 36 of 49 of major battles in interstate wars have involved at least one coalition and the majority of those coalitions have been, like the cases we study, ad hoc in nature. Understanding how command arrangements affect performance and getting organization right at the outset of wars is increasingly important.