1968
DOI: 10.1002/pol.1968.110060804
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The polymerization of N‐vinylcarbazole with metal salts in basic solvents

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Cited by 15 publications
(2 citation statements)
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“…Previous studies indicate that the polymerization behavior of metal triflates and perchlorates is superior when they operate in solution instead in a heterogeneous manner. [134][135][136][137][138][139][140][141][142][143][144][145][146][147][148] Since the number of experiments that could be conducted with Sc(OTf) 3 would be limited, a decision was made to focus on initiators that were safe to handle; water, alcohols, and carboxylic acids (Table 1). These initiators were also studied due to the fact that they all possess hydroxyl groups, function as Brønsted acids, and yet their acidity differs.…”
Section: Resultsmentioning
confidence: 99%
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“…Previous studies indicate that the polymerization behavior of metal triflates and perchlorates is superior when they operate in solution instead in a heterogeneous manner. [134][135][136][137][138][139][140][141][142][143][144][145][146][147][148] Since the number of experiments that could be conducted with Sc(OTf) 3 would be limited, a decision was made to focus on initiators that were safe to handle; water, alcohols, and carboxylic acids (Table 1). These initiators were also studied due to the fact that they all possess hydroxyl groups, function as Brønsted acids, and yet their acidity differs.…”
Section: Resultsmentioning
confidence: 99%
“…This was that activity appeared to hinge on the ability of the initiator system to dissolve in the monomer and for those systems where the coinitiator did not dissolve polymerization typically did not occur. Previous studies indicate that the polymerization behavior of metal triflates and perchlorates is superior when they operate in solution instead in a heterogeneous manner 134–148 …”
Section: Resultsmentioning
confidence: 99%