The Preparation of Organo-phosphines by the Addition of Phosphine to Unsaturated Compounds

Stiles, A. R.; Rust, Frederick F.; Vaughan, William E.

doi:10.1021/ja01133a018

Cited by 89 publications

(40 citation statements)

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“…Instead the iodo complexes 22-29 were obtained. The iron-acetyl complexes (34)(35)(36)(37) proved to be much more acidic than the related ruthenium-acetyl complexes (30)(31)(32)(33). In all the deprotonation experiments, we were unable to observe any ketene-metal intermediate.…”

Section: Resultsmentioning

confidence: 72%

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Iron(0) and ruthenium(0) complexes with tridentate phosphonite ligands and their potential for ketene formation from methyl iodide, CO and a base

Jaunky

Schmalle

Blacque

et al. 2005

Journal of Organometallic Chemistry

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Section: Resultsmentioning

confidence: 72%

“…The AIBN catalysed free radical addition [35][36][37][38] of phenylphosphine or cyclohexylphosphine with either dimethyl-or diisopropylallylphosphonite afforded the triphosphine ligands I-IV in quantitative yields (Scheme 3).…”

Section: Preparation Of the Tridentate Phosphine Ligands I-ivmentioning

confidence: 99%

Iron(0) and ruthenium(0) complexes with tridentate phosphonite ligands and their potential for ketene formation from methyl iodide, CO and a base

Jaunky

Schmalle

Blacque

et al. 2005

Journal of Organometallic Chemistry

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“…The latter can then be used to link the iron chelator (ICL670) through a peptidic reaction performed using the couple EDCI/HOBt. [53] (1)…”

Section: Preparation Of the Organophosphonate Chelatormentioning

confidence: 99%

A new sensitive organic/inorganic hybrid material based on titanium oxide for the potentiometric detection of iron(III)

Bécuwe

Rouge

Gervais

et al. 2012

Journal of Colloid and Interface Science

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“…Reactions of alkyl halides with alkali metal phosphides [39][40][41], addition reactions of olefins with PH 3 [42] or the pyrolytic cleavage of P-O bonds in RPO 2 H 2 [43] are also reported for the preparation of alkyl/aryl functionalized primary phosphines (Eqs. 5-7):…”

Section: Scheme 1 Reaction Versatility Of P-h Bonds In Primary Phospmentioning

confidence: 99%

New Vistas in Chemistry and Applications of Primary Phosphines

Katti¹,

Pillarsetty²,

Kannan³

2003

New Aspects in Phosphorus Chemistry III

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Primary phosphines (R-PH 2 ) are an important class of compounds in organophosphorus chemistry. Although discovered over a century ago, their chemistry and applications have gained prominence in recent years. This review discusses recent developments on synthesis, molecular structure, properties, and applications of primary phosphines. In particular, discussions on synthesis and properties emphasize recent results from our laboratory on the chemical architecture of amide, thioether, and carboxylate functionalized primary bisphosphines. The utility of bromo-and aminopropyl phosphines (X(CH 2 ) 3 PH 2 ; X=Br or NH 2 ) as building blocks to produce 'designer' primary phosphines that display exceptional oxidative stability is described. The review also discusses the utility of carboxylate functionalized primary phosphines for incorporation on to peptides and their potential applications in catalysis and biomedicine.

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The Preparation of Organo-phosphines by the Addition of Phosphine to Unsaturated Compounds

Cited by 89 publications

References 1 publication

Iron(0) and ruthenium(0) complexes with tridentate phosphonite ligands and their potential for ketene formation from methyl iodide, CO and a base

Iron(0) and ruthenium(0) complexes with tridentate phosphonite ligands and their potential for ketene formation from methyl iodide, CO and a base

A new sensitive organic/inorganic hybrid material based on titanium oxide for the potentiometric detection of iron(III)

New Vistas in Chemistry and Applications of Primary Phosphines

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