The Production of Vinyl Acetate Monomer as a Co-Product from the Non-Catalytic Cracking of Soybean Oil

Jones, Benjamin T.; Linnen, Michael; Tande, Brian M.; Seames, Wayne

doi:10.3390/pr3030619

Cited by 8 publications

(2 citation statements)

References 16 publications

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“…[3] In addition to these, acetate is widely used in the production of vinyl acetate monomer (VAM), which is a precursor to produce polyvinyl acetate (PVA) and polyvinyl alcohol (PVOH). [4] Acetate is also used in the production of cellulose acetate, which is used in the production of textiles, photographic film, and magnetic tape. Additionally, acetate is used as a food preservative and flavouring agent, as well as in the production of pharmaceuticals and cosmetics.…”

Section: Introductionmentioning

confidence: 99%

Multimodal Sensing of Acetate Anion by Using Anthraimidazoledione‐Based Redox‐Active Amphiphilic Dye in Aqueous Environment

Chettri,

Mondal,

Jha

et al. 2023

ChemistrySelect

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Anthraimidazoledione based amphiphilic dye is synthesized that exhibits pH‐responsive chromogenic response in aqueous environment. This entices us to investigate its anion‐responsive behavior. In pure water, the compound shows no optical response towards anions (poor sensitivity), whereas interaction with multiple anions is witnessed in acetonitrile medium (poor selectivity). Interestingly, changes in solution color from yellow to orange is observed explicitly upon addition of acetate anion, accompanied by fluorescence turn‐off response. Further, it is revealed that the acetate engaged in hydrogen bonding interaction with both imidazole −NH group and hydroxyl unit. The high basicity of acetate anion along with ‘Y‐shaped’ structure might be responsible for such unique selectivity. The present system has been involved in analyzing residual acetate in natural water samples. Low‐cost, reusable paper strips have been designed for equipment free, rapid on‐location detection of acetate.

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Section: Introductionmentioning

confidence: 99%

Multimodal Sensing of Acetate Anion by Using Anthraimidazoledione‐Based Redox‐Active Amphiphilic Dye in Aqueous Environment

Chettri,

Mondal,

Jha

et al. 2023

ChemistrySelect

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“…Soybean protein is also among plant proteins of best quality because it contains essential amino acids and holds the potential to replace proteins of animal origin [1]. Recently, the soybean has been claimed as a potential weapon against chronic diseases [2][3][4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Extraction Process of Polyphenols from Soybean (Glycine max L.) Sprouts: Optimization and Evaluation of Antioxidant Activity

Lan

Toàn

et al. 2019

Processes

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This research aimed to optimize the total polyphenol content (TPC) extracted from soybean sprout powder under different experimental parameters, including ethanol concentration (60–100% v/v), extraction temperature (40–80 °C), extraction time (15–150 min), material:solvent ratio (1:4–1:10 g/mL), the number extraction cycles (1, 2 and 3 times), the age of sprout (0–7 days), and the used part of the sprout (cotyledon, hypocotyl, or radicle). The obtained results were used in response surface methodology, in combination with a central composite design, to model the total polyphenol content (TPC) with respect to three variables, including ethanol concentration, extraction temperature, and material:solvent ratio. The experimental conditions for optimal recovery of TPC consisted of ethanol concentration of 88% (v/v), extraction temperature of 59 °C, material:solvent ratio of 1:6.5 g/mL, extraction time of 60 min, and 2 cycles of maceration. In addition, for maximal TPC, the sprout should undergo the germination of 5 days and the radicle fraction should be used. Based on the suggested optimum conditions, the obtained and verified TPC was 19.801 mg genistein (GE)/g dry weight (d.w.). The obtained dried extract also exhibited low antioxidant activity.

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The Impact of Fatty Acid Composition on Transportation Fuel Yields via the Non‐Catalytic Cracking of Triacylglyceride Oils

Seames

Linnen

Sander

et al. 2017

J Americ Oil Chem Soc

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A wide spectrum of triacylglyceride (TG) oils were decomposed in batch lab and continuous pilot‐scale reactors to generate an extensive database, which was then used to construct a model to predict the detailed composition of products generated during non‐catalytic cracking. The model was then coupled with additional simulated process steps to determine the yields of transportation products and other chemical co‐products meeting specifications of their petroleum analogs as validated with laboratory testing. A statistical study was then performed to use the model to analyze the impact that changes in TG oil composition have upon target product yields. In this study, the model was used to simulate a viable suite of products for every TG oil analyzed. The model predicts minor differences in the ratio of products from various different fatty acid compositions. For example, it was found that stearic (C18:0), oleic (C18:1), and erucic (C22:1) acids show a positive effect on fuel yields. By contrast, palmitic (C16:0), linoleic (C18:2), and linolenic (C18:3) acids have negative impacts on fuel yields. From these results, a hypothetical “ideal” TG oil was constructed. This oil turns out to have a composition that is very close to the composition of high oleic sunflower oil.

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The Production of Vinyl Acetate Monomer as a Co-Product from the Non-Catalytic Cracking of Soybean Oil

Cited by 8 publications

References 16 publications

Multimodal Sensing of Acetate Anion by Using Anthraimidazoledione‐Based Redox‐Active Amphiphilic Dye in Aqueous Environment

Multimodal Sensing of Acetate Anion by Using Anthraimidazoledione‐Based Redox‐Active Amphiphilic Dye in Aqueous Environment

Extraction Process of Polyphenols from Soybean (Glycine max L.) Sprouts: Optimization and Evaluation of Antioxidant Activity

The Impact of Fatty Acid Composition on Transportation Fuel Yields via the Non‐Catalytic Cracking of Triacylglyceride Oils

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