The properties of thin organo-tin polymer films formed by glow discharge

Tkachuk, B. V.; Marusii, N.Ya.; Laurs, Ye.P.

doi:10.1016/0032-3950(73)90099-3

Cited by 5 publications

(3 citation statements)

References 8 publications

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“…A few authors [71,150] have reported frequency and temperature depend ence of K* for PP organometallic films. For the case of several PP organotin compounds, Tkachuk et al [150] observed almost flat frequency responses up to about 1 MHz, beyond which tan δ was found to rise sharply.…”

Section: Complex Permittivitymentioning

confidence: 99%

Plasma-Polymerized Organosilicones and Organometallics

Wróbel

1990

Plasma Deposition, Treatment, and Etching of Polymers

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Section: Complex Permittivitymentioning

confidence: 99%

Plasma-Polymerized Organosilicones and Organometallics

Wróbel

1990

Plasma Deposition, Treatment, and Etching of Polymers

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“…The use of plasma deposition processes for synthesis of thin-film organometallic films is an exceedingly active research area at the present time. A notable example of this activity has been synthesis of organotin films. − No doubt, a major motivation in the tin studies, as well as in investigations of other metal-containing films, arises from the numerous potential applications of these films which include gas sensors, − optical filters, , and adhesive layers 1,2 to mention but a few of the uses which have been identified.…”

Section: Introductionmentioning

confidence: 99%

Pulsed Plasma Polymerization of Tetramethyltin: Nanoscale Compositional Control of Film Chemistry

Chen¹,

Rajeshwar²,

Timmons³

et al. 1996

Chem. Mater.

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The pulsed plasma polymerization of tetramethyltin monomer was studied as a function of the radio frequency (rf) duty cycle employed, all other plasma variables being held constant. Progressive increases in the relative tin content of the plasma deposited films were observed with systematic decreases in the rf duty cycles employed during film formation. The variations in tin content of these films were documented by XPS, FT-IR, TEM, AFM, and electrochemical analyses. A particularly interesting aspect of this work is the microstructure of the films which reveals spherical tin particles of essentially uniform diameters (20-30 nm) independent of the duty cycle during deposition. The increasing metal content in these films with decreasing duty cycle corresponds to increased aggregation of these nanosized particles into progressively larger sized clusters. The results obtained are supportive of the use of the variable duty cycle pulsed plasma deposition technique as a new route to improved nanoscale film chemistry control in the synthesis of organometallic composite films.

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“…The extent to which they occur is dependent upon the chemical structure of the starting material and on the condition of the discharge. Tkachuk et al3,4 have reported that organotin polymer films prepared in a glow discharge can be used as insulating layers on microelectronic devices, as protective coatings, and as intermediate adhesive layers. Subsequent thermal treatment of these coatings can result in new films of very different properties.…”

Section: Introductionmentioning

confidence: 99%