The Radiation-Induced Addition Reaction of Dialkyl Phosphonates to Chlorofluoroolefins

Radical telomerization of 3,3,3-trifluoropropene with diethyl hydrogen phosphonate: Characterization of the first telomeric adducts and assessment of the transfer constants

“…They can also act as additives for polymers [8,9]. Many investigations dealing with the synthesis of R F P(O)(OR) 2 have been described in the literature [10][11][12][13][14][15][16][17][18][19]. Among these methods, the telomerization reaction has proved to be an easy method to prepare such derivatives.…”

“…tetrafluoroethylene (TFE) [10][11][12], chlorotrifluoroethylene (CTFE) [20], and vinylidene fluoride (VDF) [21] with phosphonate-containing transfer agents (e.g., dialkyl hydrogen phosphonates). They also react with monomers bearing phosphonate functionality (e.g.…”

Ethylene-tetrafluoroethylene (ETFE) cotelomer iodides and their transformation to surface protection intermediates

“…Many telomers, such as TFE telomers [11][12][13][14], CTFE telomers [15][16][17], vinylidene fluoride telomers [18], trifluoropropylene telomers [19], and ethylene telomers [20], have been reported. On the other hand, there are very limited examples related to the cotelomerization that provide fluorinated cotelomer [21].…”

Original fluorinated surfactants potentially non-bioaccumulable

“…These latters can be produced by the radical telomerization of various fluoroalkenes (tetrafluoroethylene, hexafluoropropylene, vinylidene fluoride, chlorotrifluoroethylene, dichlorodifluoroethylene), [55][56][57][58][59][60][61][62][63] with dialkyl hydrogenophosphate as listed in Table 2 and Scheme 5:…”