The reaction of σ-vinylpalladium complexes with alkyllithiums. Stereospecific syntheses of olefins from vinyl halides and alkyllithiums

Yamamura, Masaaki; Moritani, Ichiro; Murahashi, Shun‐Ichi

doi:10.1016/s0022-328x(00)89636-9

Cited by 255 publications

(81 citation statements)

References 18 publications

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“…While earlier reports of reactions with harsh reagents such as organolithium and Grignard reagents exist, 11,12 the generally accepted landmark in the development of organometallic C-C coupling reactions was the publication by two independent researchers on the palladium catalyzed coupling of aryl halides with terminal olefins 2, 13 -the Heck reaction. As illustrated in Figure 1, after this point many C-C coupling reactions were quickly developed, including the Sonogashira, 14 Stille, 15 and Suzuki-Miyaura 16 couplings.…”

Section: Conventional C-c Coupling Reactionsmentioning

confidence: 99%

Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: Elucidation of the Pt particle size effect on reaction kinetics

Пушкарев

Alayoǧlu

et al. 2012

Journal of Catalysis

125

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. (2012) 'Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts : elucidation of the Pt particle size eect on reaction kinetics.', Journal of catalysis., 292 . pp. 64-72. Further information on publisher's website:http://dx.doi.org/10.1016/j.jcat.2012.04.022Publisher's copyright statement: This is the author's version of a work that was accepted for publication in Journal of Catalysis. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reected in this document. Changes may have been made to this work since it was submitted for publication. A denitive version was subsequently published in Vladimir V. Pushkarev, Kwangjin An, Selim Alayoglu, Simon K. Beaumont, Gabor A. Somorjai (2012) Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: Elucidation of the Pt particle size eect on reaction kinetics, Journal of Catalysis, 292, pp. 64-72, http://dx.doi.org/10.1016/j.jcat.2012.04.022. Additional information:Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.

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Section: Conventional C-c Coupling Reactionsmentioning

confidence: 99%

Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: Elucidation of the Pt particle size effect on reaction kinetics

Пушкарев

Alayoǧlu

et al. 2012

Journal of Catalysis

125

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“…(Sonogashira, 1975). (Murahashi, 1975 [94] . Suzuki, Miyaura and coworkers, in contrast, unraveled the benefi cial effect of added bases in palladiumcatalyzed cross -coupling reactions between alkenylboranes and organic halides [95] .…”

Section: Syntheses Of Substituted (Hetero)arenes and The Contents Ofmentioning

confidence: 99%

Arylation Reactions: A Historical Perspective

Ackermann

2009

Modern Arylation Methods

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“…Palladium, the most widely used metal, enables the synthesis of complex and functionalized organic molecules and its chemistry possesses different interesting facets such as heterogeneous and homogeneous catalysis under mild experimental conditions compatible with many functional groups [1][2][3][4][5]. Several palladium catalyzed cross-coupling reactions such as Heck [6][7][8][9][10][11], Suzuki [12][13][14][15][16], Sonogashira [17][18][19][20][21], Stille [22][23][24][25], Hiyama [26], Negishi [27], Kumada [28], Murahashi [29] and Buchwald-Hartwig [30,31] have been developed over the years.…”

Section: Introductionmentioning

confidence: 99%

Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling in Continuous Flow

et al. 2017

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Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry and Suzuki-Miyaura reactions are the most widely used protocols. For a decade, green chemistry and particularly catalysis and continuous flow, have shown immense potential in achieving the goals of "greener synthesis". To date, it seems difficult to conceive the chemistry of the 21st century without the industrialization of continuous flow process in the area of pharmaceuticals, drugs, agrochemicals, polymers, etc. A large variety of palladium Suzuki-Miyaura cross-coupling reactions have been developed using a continuous flow sequence for preparing the desired biaryl derivatives. Our objective is to focus this review on the continuous flow Suzuki-Miyaura cross-coupling using homogeneous and heterogeneous catalysts.

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The reaction of σ-vinylpalladium complexes with alkyllithiums. Stereospecific syntheses of olefins from vinyl halides and alkyllithiums

Cited by 255 publications

References 18 publications

Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: Elucidation of the Pt particle size effect on reaction kinetics

Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: Elucidation of the Pt particle size effect on reaction kinetics

Arylation Reactions: A Historical Perspective

Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling in Continuous Flow

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