The Reactions of Carbene Complexes of Transition Metals with Unsaturated Hydrocarbons

Syatkovskii, A. I.; Babitskii, B. D.

doi:10.1070/rc1984v053n07abeh003087

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Iron-stabilized Carbenes In Organic Synthesis1

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1990

1992

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Cited by 4 publications

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“…Although carbene complexes have been studied intensively for more than 2 decades, it is only very recently that useful applications of these complexes to organic synthesis have been developed [ 137 , 139 , 149 , 150 – 154 ].…”

Section: Iron-stabilized Carbenes In Organic Synthesismentioning

confidence: 99%

New chemical and stereochemical applications of organoiron complexes

Fatiadi

1991

J. RES. NATL. INST. STAN.

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The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η5-C5H5) Fe(CO)(PPh3)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO)3 group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

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Section: Iron-stabilized Carbenes In Organic Synthesismentioning

confidence: 99%