Carbonization and activation have been exploited as an economic and efficient approach toward the production of porous activated carbon monolith derived from green stem of cassava (GSC). In addition, ZnCl 2 was used as a chemical activator agent at various concentrations, therefore serving as a key factor in the development of porous carbon. The carbonization process (N 2) was integrated with physical activation (CO 2), and then N 2 sorption, scanning electron microscopy, X-ray diffraction, energy dispersive X-ray were examined to evaluate the specific surface area, pore structure characteristic, morphology structure, crystallinity, and the surface element, respectively. Furthermore, cyclic voltammetry was used to measure the electrochemical performance, through a two-electrode system in 1M H 2 SO 4. Therefore, the synthesized porous activated carbon exhibits a micropores-mesopores combination, and the optimized sample demonstrated nanosheet and nanofiber structures. The results show a high electrochemical behavior in 1M H 2 SO 4 electrolytes, by the electrodes, with specific capacitance, energy, and power densities of 164.58 F g −1 , 22.86 Wh kg −1 , and 82.38 W kg −1 , respectively. This route confirms the opportunity of using novel GSC in the production of porous carbon monolith with nanosheet/nanofiber structure for supercapacitor applications. K E Y W O R D S activated carbon, carbon porous, green stem of cassava, monolith, supercapacitor 1 | INTRODUCTION Green, renewable, and sustainable sources of energy systems are obtainable through the conversion of wind, water, and solar energy, 1 hence proper capture and storage is required for environmental friendly and economic application. 2 Meanwhile, supercapacitors possessing high power density, high charge-discharge rate, long cycle life, have the ability to store energy in the form of electric charges, 3 by providing a performance between capacitors and batteries. Conversely, the difference between both is that capacitors store and deliver energy incredibly quickly, while batteries have an ability to store high energy densities and also high voltages. 4 However, the main challenge of supercapacitor is related to the energy density entry through the narrow gap of batteries. Several electrode materials have been developed and suggested to improve energy density, power density, and cycle life of supercapacitor, 5 and three types were identified. These were then classified into carbonaceous