The Relation between Tourniquet Hypertension and Bispectral Index in Patients Undergoing a Total Knee Arthroplasty

Cover Feature: Capture of Gaseous Iodine in Isoreticular Zirconium‐Based UiO‐n Metal‐Organic Frameworks: Influence of Amino Functionalization, DFT Calculations, Raman and EPR Spectroscopic Investigation (Chem. Eur. J. 14/2022)

“…t (F = 0.90) Previous experimental adsorption investigations [26] of molecular iodine in cyclohexane liquid phase, have shown similar results concerning the UiO-66_H, UiO-66_Br and UiO-66_NO2 members. But they differed for the UiO-66_(OH)2 and UiO-66_NH2 compounds, for which identical higher iodine uptakes were reported.…”

“…The redox I2 → I3conversion was unexpected in our system and was observed in a few previous studies, [24] but was not mentioned in other works. [22,26] This reaction will be further characterized by Raman and EPR spectroscopies.…”

“…[24] These reports dealt with the use of iodine vapor generated in a closed cell, in contact with the considered powdered UiO-n compounds, which are then weighted for the estimation of iodine uptake. For this UiO-n series, other works also described the influence of defects in the Hf-UiO-66 solids [25] or the effects of the nature of a wide variety of functional organic groups decorating the ditopic ligands in UiO-66, [26] by analyzing the iodine sorption from liquid phase using cyclohexane as solvent. The aim of the present contribution is the investigation of the kinetics of gaseous iodine adsorption of the series of Zr-UiO-n.…”

Cluster‐Based Crystalline Materials for Iodine Capture

“…Lee and Park tested the iodine adsorption behavior of two different types of isostructural organic frameworks, UiO-66-X series (X=H, Br, NO 2 , NH 2 , (OH) 2 , and (COOH) 2 ) and M 2 (m-DOBDC) series. [92] Among all groups, the carboxylic acid group (À COOH) exhibits the fastest adsorption kinetics and highest adsorption capacity. Recently, a series of Th-UiO-66 MOFs were modified with different functional groups (NH 2 , (NH 2 ) 2 , OH, CH 3 , OCH 3 , (OCH 3 ) 2 , NO 2 , Cl, Br, Cl 2 , Br 2 and (CF 3 ) 2 ) as standard models to systematically study the effect of substituents on iodine adsorption in solution and vapor state (Figure 4a).…”