1951
DOI: 10.5254/1.3543063
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The Role of Intermolecular Forces in the Mechanism of High-Elastic Deformation. I. The Molecular Mechanism and an Equation for the Kinetics of High Elastic Deformation

Abstract: 1. The molecular mechanism of the relaxation of deformation of high-elastic polymers has been studied. 2. It is shown that the slow relaxation, which is typical of high-elastic polymers, may be best explained as a restoration process, which either partial or complete (depending on the degree of development of side chains in the molecular structure formed by the main valence chains) of the balanced configurations of the molecular chains. 3. It is shown that the rate of the relaxation process in this case is det… Show more

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1951
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“…Jenckel [505] ] has reviewed the plastic-elastic behavior of high polymeric materials and has shown how this behavior may relate to their chemical structure. The importance of molecular forces in the mechanism of elastic deformation [491,539] has also been discussed.…”
Section: Structure and Properties Of Synthetic Fibersmentioning
confidence: 99%
See 1 more Smart Citation
“…Jenckel [505] ] has reviewed the plastic-elastic behavior of high polymeric materials and has shown how this behavior may relate to their chemical structure. The importance of molecular forces in the mechanism of elastic deformation [491,539] has also been discussed.…”
Section: Structure and Properties Of Synthetic Fibersmentioning
confidence: 99%
“…Jenckel [505] ] has reviewed the plastic-elastic behavior of high polymeric materials and has shown how this behavior may relate to their chemical structure. The importance of molecular forces in the mechanism of elastic deformation [491,539] has also been discussed.Studies of the dynamic modulus and energy loss per cycle observed in the dynamic loading of high polymeric materials have received considerable attention during the past year. Treatments of linear visco-elastic systems have been made by Cini [488], Thorne [534], Roscoe [526], Gross [500], Skudrzyk [529], and Lethersich and Pelzer [509].…”
mentioning
confidence: 99%