2019
DOI: 10.1021/acs.chemrev.8b00733
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The Role of Ligands in the Chemical Synthesis and Applications of Inorganic Nanoparticles

Abstract: The design of nanoparticles is critical for their efficient use in many applications ranging from biomedicine to sensing and energy. While shape and size are responsible for the properties of the inorganic nanoparticle core, the choice of ligands is of utmost importance for the colloidal stability and function of the nanoparticles. Moreover, the selection of ligands employed in nanoparticle synthesis can determine their final size and shape. Ligands added after nanoparticle synthesis infer both new properties … Show more

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Cited by 876 publications
(816 citation statements)
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“…Here one has to keep in mind that changes in the ionic strength of the dispersion media will also have an impact on the electrostatic stabilization. Therefore, this parameter will also be investigated, together with surface ligands that have been reported for colloidal stability via steric repulsion, in the near future.…”
Section: Resultsmentioning
confidence: 99%
“…Here one has to keep in mind that changes in the ionic strength of the dispersion media will also have an impact on the electrostatic stabilization. Therefore, this parameter will also be investigated, together with surface ligands that have been reported for colloidal stability via steric repulsion, in the near future.…”
Section: Resultsmentioning
confidence: 99%
“…Although most of the reported procedures offer obvious advantages, they suffer from some drawbacks i.e. the use of high temperatures, expensive metal precursors, use of expensive or toxic catalysts, the use of a large quantity of volatile and toxic organics, formation of by‐products, product contamination and difficulty in catalyst separation from the reaction media and recycling . Therefore, the search to find a new, green, efficient and reusable catalytic system for the synthesis of polyhydroquinoline structural scaffolds is an important challenge for organic‐synthetic chemists in catalysis research.…”
Section: Introductionmentioning
confidence: 99%
“…As such, several strategies have been implemented that include the use of polymers, surfactants and chelating agents to protect the nanoparticles' surfaces and thereby to confer colloidal stability under variable chemical conditions . In this context, dendrimers have also been explored as templating and stabilizing agents for a wide variety of metal nanoparticles , , . The polyamido(amine) (PAMAM) dendrimer belong to the class of dendrimers that have been extensively used for the preparation of metal nanoparticles, either monometallic or bimetallic systems.…”
Section: Introductionmentioning
confidence: 99%