1988
DOI: 10.1021/ac00158a019
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The role of metastable atoms in glow discharge ionization processes

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Cited by 57 publications
(17 citation statements)
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“…Solanki et al 14 investigated the excitation of ion laser transitions in noble gas mixtures in hollow cathode discharges and reported that the dominant excitation mechanism of noble-gas ions was found to be collisions of the second kind between the ground-state noble-gas ions and neon metastables. Evidence for the role of Penning ionization in very low current (1-5 mA), low pressure ($1 hPa) glow discharges was provided by Hess and Harrison 15 using neon and argon as discharge gases. Using various models Bogaerts and Gijbels have used a mathematical simulation to compare neon and argon as discharge gases in a dc glow discharge.…”
Section: Introductionmentioning
confidence: 99%
“…Solanki et al 14 investigated the excitation of ion laser transitions in noble gas mixtures in hollow cathode discharges and reported that the dominant excitation mechanism of noble-gas ions was found to be collisions of the second kind between the ground-state noble-gas ions and neon metastables. Evidence for the role of Penning ionization in very low current (1-5 mA), low pressure ($1 hPa) glow discharges was provided by Hess and Harrison 15 using neon and argon as discharge gases. Using various models Bogaerts and Gijbels have used a mathematical simulation to compare neon and argon as discharge gases in a dc glow discharge.…”
Section: Introductionmentioning
confidence: 99%
“…Under GD low-pressure conditions, metastable atoms transfer their energy through inelastic collisions (PI) to analyte atoms for several milliseconds. 25 In case of argon as plasma gas, the energy amounts to $12 eV implying that ions of intact molecules and only a few fragments are formed if the ionization potential of the analyte falls below this value.…”
Section: Introductionmentioning
confidence: 99%
“…However, previous studies on argon glow discharges have shown that the argon atom numberdensity is y10 16 and the argon metastable number-density from 10 11 -10 12 cm 23 . 2,26,27 These previous studies were not Fig. 6 ''Linearized'' Thomson-scattering spectrum.…”
Section: Resultsmentioning
confidence: 91%