The Role of β-Cyclodextrin in the Textile Industry—Review

Bezerra, Fabrício Maestá; Arias, Manuel José Lis; Firmino, Helen Beraldo; Silva, Joyce Gabriella Dias da; Valle, Rita de Cássia Siqueira Curto; Valle, José Alexandre Borges; Scacchetti, Fábio Alexandre Pereira; Tessaro, André Luiz

doi:10.3390/molecules25163624

Cited by 75 publications

(48 citation statements)

References 180 publications

(291 reference statements)

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“…The formation of molecular inclusion complexes using CDs is a very common microencapsulation approach, widely investigated for different purposes [ 79 , 80 , 81 , 82 ]. It is based on the stoichiometric hydrophobic interactions via dynamic equilibrium between CDs and the complexed substance, which is entrapped in the hydrophobic cavity of CDs [ 83 ].…”

Section: Methods Of Preparation For Micro/nanoencapsulation Of Flamentioning

confidence: 99%

Encapsulation of Flavours and Fragrances into Polymeric Capsules and Cyclodextrins Inclusion Complexes: An Update

2020

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Flavours and fragrances are volatile compounds of large interest for different applications. Due to their high tendency of evaporation and, in most cases, poor chemical stability, these compounds need to be encapsulated for handling and industrial processing. Encapsulation, indeed, resulted in being effective at overcoming the main concerns related to volatile compound manipulation, and several industrial products contain flavours and fragrances in an encapsulated form for the final usage of customers. Although several organic or inorganic materials have been investigated for the production of coated micro- or nanosystems intended for the encapsulation of fragrances and flavours, polymeric coating, leading to the formation of micro- or nanocapsules with a core-shell architecture, as well as a molecular inclusion complexation with cyclodextrins, are still the most used. The present review aims to summarise the recent literature about the encapsulation of fragrances and flavours into polymeric micro- or nanocapsules or inclusion complexes with cyclodextrins, with a focus on methods for micro/nanoencapsulation and applications in the different technological fields, including the textile, cosmetic, food and paper industries.

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Section: Methods Of Preparation For Micro/nanoencapsulation Of Flamentioning

confidence: 99%

Encapsulation of Flavours and Fragrances into Polymeric Capsules and Cyclodextrins Inclusion Complexes: An Update

2020

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“…Therefore, they will not be discussed in this article. Moreover, the benefits resulting from encapsulation of various molecules in the form of CD complexes will not be described here, as there are other (recent and excellent) reviews on this topic [17][18][19]. Therefore, this paper will begin with a brief summary of the concepts of MD simulations, followed by solutions that are frequently used to properly model the CD complexes by its means.…”

Section: Molecular Modeling Of CD Host-guest Complexes-theoretical and Practical Aspectsmentioning

confidence: 99%

Application of Molecular Dynamics Simulations in the Analysis of Cyclodextrin Complexes

Mazurek

Szeleszczuk

Gubica

2021

IJMS

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Cyclodextrins (CDs) are highly respected for their ability to form inclusion complexes via host–guest noncovalent interactions and, thus, ensofance other molecular properties. Various molecular modeling methods have found their applications in the analysis of those complexes. However, as showed in this review, molecular dynamics (MD) simulations could provide the information unobtainable by any other means. It is therefore not surprising that published works on MD simulations used in this field have rapidly increased since the early 2010s. This review provides an overview of the successful applications of MD simulations in the studies on CD complexes. Information that is crucial for MD simulations, such as application of force fields, the length of the simulation, or solvent treatment method, are thoroughly discussed. Therefore, this work can serve as a guide to properly set up such calculations and analyze their results.

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“…The existence of two reactive groups in EPI allows its bivalent binding to cyclodextrins, generating hydrophilic polymeric networks (hydrogels) with multiple CD molecules linked by repeating glyceryl moieties [24,25,28,35,[38][39][40][41][42][43][44][45]. These materials display high adsorption capability, are efficient in the removal of water contaminants present at trace levels, and show relatively fast kinetics [9,25,26,29,30,33,[46][47][48][49][50][51][52].…”

Section: Cyclodextrin-based Polymers In Pollutant Removalmentioning

confidence: 99%

Cyclodextrin Polymers and Cyclodextrin-Containing Polysaccharides for Water Remediation

et al. 2021

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Chemical pollution of water has raised great concerns among citizens, lawmakers, and nearly all manufacturing industries. As the legislation addressing liquid effluents becomes more stringent, water companies are increasingly scrutinized for their environmental performance. In this context, emergent contaminants represent a major challenge, and the remediation of water bodies and wastewater demands alternative sorbent materials. One of the most promising adsorbing materials for micropolluted water environments involves cyclodextrin (CD) polymers and cyclodextrin-containing polysaccharides. Although cyclodextrins are water-soluble and, thus, unusable as adsorbents in aqueous media, they can be feasibly polymerized by using different crosslinkers such as epichlorohydrin, polycarboxylic acids, and glutaraldehyde. Likewise, with those coupling agents or after substituting hydroxyl groups with more reactive moieties, cyclodextrin units can be covalently attached to a pre-existing polysaccharide. In this direction, the functionalization of chitosan, cellulose, carboxymethyl cellulose, and other carbohydrate polymers with CDs is vastly found in the literature. For the system containing CDs to be used for remediation purposes, there are benefits from a synergy that arises from (i) the ability of CD units to interact selectively with a broad spectrum of molecules, forming inclusion complexes and higher-order supramolecular assemblies, (ii) the functional groups of the crosslinker comonomers, (iii) the three-dimensional structure of the crosslinked network, and/or (iv) the intrinsic characteristics of the polysaccharide backbone. In view of the most recent contributions regarding CD-based copolymers and CD-containing polysaccharides, this review discusses their performance as adsorbents in micropolluted water environments, as well as their interaction patterns, addressing the influence of their structural and physicochemical properties and their functionalization.

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The Role of β-Cyclodextrin in the Textile Industry—Review

Cited by 75 publications

References 180 publications

Encapsulation of Flavours and Fragrances into Polymeric Capsules and Cyclodextrins Inclusion Complexes: An Update

Encapsulation of Flavours and Fragrances into Polymeric Capsules and Cyclodextrins Inclusion Complexes: An Update

Application of Molecular Dynamics Simulations in the Analysis of Cyclodextrin Complexes

Cyclodextrin Polymers and Cyclodextrin-Containing Polysaccharides for Water Remediation

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