At present, there are two models of pathological personality represented in two measurement instruments, the Personality Inventory for DSM-5 (PID-5) and the Personality Inventory for ICD-11 (PiCD). Although both instruments have shown high convergence, the PID-5 has the advantage of including facets that might offer greater predictive capacity. An alternative to the PiCD has recently been proposed to overcome this drawback, namely the Five-Factor Personality Inventory for ICD-11 (FFiCD). The present study aims to explore its internal structure and to offer additional validity evidence. Data were collected for a total of 1,409 community individuals from two populations in Spain. They responded to the FFiCD, PiCD, the PID-5/SF, and measures of personality functioning and personality disorder screening (Level of Personality Functioning Scale Self-Report [LPFS-SR] and International Personality Disorder Examination [IPDE]). The internal structure of the FFiCD was analyzed through exploratory factor analysis with oblique and bifactor rotations. The predictive capacity of the domains and facets was examined. The structure reported in the original study was replicated, as were the convergent validity data with respect to the PID-5/SF and the PiCD. Facets were grouped into four factors corresponding to the theoretical domains, including a bipolar Anankastia/Disinhibition factor. High correlations were found with the LPFS-SR, and the patterns of relationships with the IPDE shed light on which aspects of pathological personality contribute most to the 10 traditional personality disorders. In general, validity evidence is provided to support the use of the FFiCD, though four of the 20 facets merit revision so that a simpler factor structure can be obtained.