(1) Background: Operational properties and durability of dies in different metal-forming processes significantly depend on their surface quality. Major die failures are related to surface damage due to heat checking cracks, wear, etc. Thereby, strengthening of the working surfaces of dies for hot bending, stamping, forging, and die casting processes is an urgent engineering challenge. Surface alloying with high-energy beams improves the properties of steel products. In these processes, the alloying powders and the treated surfaces can be remelted by electron beam within a short time while the bulk structure of the component remains unchanged, resulting in minimal distortion. The paper presents the results of the electron beam surface alloying (EBSA) of H21 and L6 tool steels with the treatment pastes containing boron carbide and aluminum powders. (2) Methods: Two types of pastes were used for surface alloying: a single-component (B4C) paste and a two-component (B4C+Al) one. The microstructure, microhardness, wear resistance, and elemental and phase composition of the layers obtained on steels were investigated. (3) Results: Four layers up to 0.4 mm thick were distinguished on the surface of the steels after the EBSA. Metallographic analysis showed coarse dendrite formation in the layers embedded in matrices of a eutectic or a solid solution. Microhardness of the steels after the two-component EBSA was higher than after B4C EBSA, which was related to a higher concentration of hard phases, such as iron borides and carbides. In addition, aluminum boride was revealed by the XRD analysis on L6 steel after B4C+Al EBSA. (4) Conclusions: Wear test indicated that the most resistant samples were H21 steel after single B4C EBSA and L6 steel after B4C+Al EBSA. Both samples contained carbon particles in the layer contributing to the high wear resistance as a lubricant. The conducted research is beneficial for mechanical engineering, automotive engineering, medical technology, aerospace engineering, and related industries, where coatings with high microhardness, wear resistance, and surface quality are demanded.
