Thermal
flooding by steam injection was a traditional method for
exploiting heavy oil. The produced liquid was a highly stable water-in-oil
or oil-in-water emulsion in several oilfields. In this work, we focused
on studying the effect of high temperature on the stability of an
emulsion system involving two typical crude oils (heavy crude oil
and light crude oil) and brine. It was impossible to directly measure
the interfacial viscoelastic modulus because of the high viscosity
of the heavy oil. In order to solve this problem and analyze the contribution
of those fractions to the formation of stable emulsions, the heavy
crude oil was divided into three cuts: remaining fraction, resin,
and asphaltene. The model oils were prepared from the mixture of several
heavy crude oil fractions with kerosene:xylene (1:1 v/v) to investigate
the high-temperature behaviors of their emulsions. The stability was
evaluated through a high-temperature–high-pressure (HTHP) visual
pressure–volume–temperature cell, and a temperature
up to 200 °C was achieved. The automatic pendant drop technique
was used to analyze the interfacial rheology of model oils/brine system
under HTHP conditions. With increasing formation temperature, the
kinetically stable heavy oil emulsion had a much higher viscosity.
The stabilities of heavy crude oil and light crude oil emulsions had
opposite trends as the formation temperature increased. The stabilities
of different model oils indicated that the mass fraction of asphaltene
was responsible for the stability of emulsions at high temperature.
With increasing temperature, the interfacial viscoelastic properties
stabilized by 4.0 wt % asphaltenes had an increasing trend, but the
stability of remaining fraction, resin, and 0.4 wt % asphaltene had
a decreasing trend. The mechanism of formation of a stable and more
rigid interfacial film was revealed by the effect of high temperature
on asphaltene aggregation and water molecules.