The synthesis and electrochemical behaviour of water soluble manganese phthalocyanines: Anion radical versus Mn(I) species

Sehlotho, Nthapo; Durmuş, Mahmut; Ahsen, Vefa; Nyokong, Tebello

doi:10.1016/j.inoche.2008.01.029

Cited by 65 publications

(24 citation statements)

References 16 publications

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“…2-Mercaptopyridine was purchased from Fluka. 3-Nitrophthalonitrile (1) [30], 4,5-dichlorophthalonitrile (2) [31], 3-(2-mercaptopyridine)phthalonitrile (3) [32], 2,(3)-tetra-(2-mercaptopyridine) phthalocyaninatozinc (II) (7) [33] and quaternized 2,(3)-tetra-(2-mercaptopyridine)phthalocyaninato zinc (II) (10) [33] were synthesized and purified according to literature procedures. ZnPcS mix containing a mixture of differently sulfonated derivatives was synthesized as reported before [34].…”

Section: Methodsmentioning

confidence: 99%

Water-soluble quaternized mercaptopyridine-substituted zinc-phthalocyanines: Synthesis, photophysical, photochemical and bovine serum albumin binding properties

et al. 2011

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Section: Methodsmentioning

confidence: 99%

Water-soluble quaternized mercaptopyridine-substituted zinc-phthalocyanines: Synthesis, photophysical, photochemical and bovine serum albumin binding properties

et al. 2011

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“…3-(2-Mercaptopyridine)phthalonitrile compound was synthesized, purified and characterized according to literature procedure. 20 The synthesis of the 3-(2-Mercaptopyridine) phthalonitrile is given in Scheme 1.…”

Section: Experimental and Theoretical Methodsmentioning

confidence: 99%

Experimental and Computational Approaches to the Molecular Structure of 3-(2-Mercaptopyridine)phthalonitrile

Tanak¹,

Köysal²,

Işık³

et al. 2011

Bulletin of the Korean Chemical Society

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The compound 3-(2-Mercaptopyridine)phthalonitrile has been synthesized and characterized by IR, UV-vis, and X-ray single-crystal determination. The molecular geometry from X-ray determination of the title compound in the ground state has been compared using the Hartree-Fock (HF) and density functional theory (DFT) with the 6-31G(d) basis set. The calculated results show that the DFT and HF can well reproduce the structure of the title compound. The energetic behavior of the title compound in solvent media was examined using the B3LYP method with the 6-31G(d) basis set by applying the Onsager and polarizable continuum model. Using the TD-DFT and TD-HF methods, electronic absorption spectra of the title compound have been predicted and good agreement with the TD-DFT method and the experimental determination was found. The predicted nonlinear optical properties of the title compound are much greater than those of urea. Besides, molecular electrostatic potential of the title compound were investigated by theoretical calculations. The thermodynamic properties of the compound at different temperatures have been calculated and corresponding relations between the properties and temperature have also been obtained.

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“…Preparative thin layer chromatography was performed on silica gel 60 P F 254 . 3-Nitrophthalonitrile (1) [33], 4-nitrophthalonitrile (2) [34], 3-(2-mercaptopyridine) phthalonitrile (3) and 4-(2-mercaptopyridine) phthalonitrile (4) [35] were synthesized and purified according to literature procedures.…”

Section: Methodsmentioning

confidence: 99%

Water-soluble cationic gallium(III) and indium(III) phthalocyanines for photodynamic therapy

Durmuş¹,

Ahsen²

2010

Journal of Inorganic Biochemistry

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122

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The synthesis and electrochemical behaviour of water soluble manganese phthalocyanines: Anion radical versus Mn(I) species

Cited by 65 publications

References 16 publications

Water-soluble quaternized mercaptopyridine-substituted zinc-phthalocyanines: Synthesis, photophysical, photochemical and bovine serum albumin binding properties

Water-soluble quaternized mercaptopyridine-substituted zinc-phthalocyanines: Synthesis, photophysical, photochemical and bovine serum albumin binding properties

Experimental and Computational Approaches to the Molecular Structure of 3-(2-Mercaptopyridine)phthalonitrile

Water-soluble cationic gallium(III) and indium(III) phthalocyanines for photodynamic therapy

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