The synthesis of epoxy resin coated Al₂O₃composites for selective laser sintering 3D printing

Abstract

Purpose To prepare a new type of composite for selective laser sintering 3D printing, the surface of Al2O3 nanoparticles was modified by the coupling agent (3-methacryloxypropyl)-trimethoxy silane (KH570) before coated with thermoplastic epoxy resin (TER). Design/methodology/approach Laser diffraction confirmed that the size distribution of prepared powder materials in this study ranged between 20 to 80 µm. Thermogravimetric analysis (TGA) showed that the loading of organic matter was below 5 per cent. Fourier transform infrared spectroscopy indicated that the silane coupling agent molecule bound strongly with the alumina. X-ray diffraction confirmed the prepared powder materials to be α-alumina. Through the angle of repose (AOR) test, the AOR = 18.435º was obtained, suggesting the high flowability of prepared powder materials. Scanning electron microscopy (SEM) observation demonstrated that the shape of the prepared powder materials was sphere-like grains. Findings Molding properties of prepared powder materials were studied on the basis of particle size distribution, particle size, sphericity, crystal structure and the reaction mode of the TER. This prepared powder materials can be well applied to the production of epoxy resin-coated Al2O3 composite parts with high precision and good mechanical performance. Originality/value This composite can be well applied to the production of epoxy resin-coated Al2O3 composite parts with high precision and good mechanical performance.

TUL-C04-Producción de piezas de alúmina mediante manufactura aditiva

“…De estas piezas se obtuvieron muestras para ser analizadas en un equipo SETSYS Evolution TGA-DTA/DSC SETARAM con el propósito de verificar, mediante un análisis termogravimétrico (TGA), la eliminación del binder. El programa de la rampa de temperaturas utilizado es similar al reportado por Yang et al (2018), en el que se incrementó la temperatura 5 o C por minuto a partir de la temperatura ambiente hasta alcanzar los 600 ºC en una atmósfera de nitrógeno, con los resultados descritos en los siguientes termogramas (véase figuras 10, 11 y 12).…”