The Synthesis of Polyguanamines

Ebihara, Shigeyoshi; Okata, Akira

doi:10.5059/yukigoseikyokaishi.27.1095

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“…Such conformational changes make poly(γ-glutamate)s informative structural and functional models for biopolymers. The potential commercial and scientific applications of poly(γ-glutamates) have been exploited by many researchers. − …”

Section: Introductionmentioning

confidence: 99%

Synthesis of Paucidisperse Poly(γ-benzyl-α,l-glutamate) Oligomers and Star Polymers with Rigid Arms

et al. 2001

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The synthesis of highly uniform gamma-benzyl-alpha,L-glutamate (BLG) oligomers via a convergent solution phase approach is reported. BLG oligomers were produced with designed lengths of 4, 8, 12, and 16 as a first step to production of BLG-4-mer and BLG-8-mer rod stars. The star oligomers were purified by size-exclusion chromatography and reversed phase HPLC, and characterized by MALDI-TOF mass spectrometry and reversed phase HPLC. These star-shaped BLG oligomers could be used as initiators for growing larger stars.

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