electrolyzers can produce high-purity H 2 with rapid response time, which is very suitable to be integrated with intermittent renewable energy sources. PEM fuel cells can efficiently convert H 2 and O 2 to electric power for driving the next generation vehicles. CO 2 electrolyzers convert electric power to various fuels and chemical feedstocks.Many SPE electrochemical energy conversion devices involve heterogeneous reaction, which calls for efficient multiphase transport in porous transport electrode (PTE) materials. In one aspect, bad mass transport cause insufficient reactant supply and product blockage on the reaction interfaces, finally leads to a depressed energy conversion efficiency. [12][13][14] Although, some publications reported that the gas product may introduce local microconvection to enhance the reactant supply in liquid electrolyte system. [12,15,16] Considering the solid state of SPE, the micro-convection impacts are supposed to be limited. In another aspect, mass transport in PTE materials has great impacts on reaction selectivity in some competing reaction. [17] For example, Xia et al., found that increasing the local O 2 concentration can greatly enhance the Faraday efficiency of H 2 O 2 production. [18] Optimizing porous transport materials is a good way to enhance mass transport in SPE electrochemical energy conversion devices. Researchers develop various porous transport layers (PTLs) or gas diffusion layers (GDLs) to enhance the multi-phase mass transport from the flow field to the reaction interface, including fiber based GDLs/PTLs, [19] powder based GDLs/PTLs, [20] mesh based GDLs/PTLs, [21] or some tailored GDLs/PTLs. [22,23] In addition to mass transport in PTLs/GDLs, the mass transport in PTE/SPE interface is more essential for SPE based energy conversion devices. Because the PTE/SPE interface is closer to reaction sites. However, due to the limited in situ mass transport characterization methods, the mass transport at PTE/SPE interface is overlooked. In situ electrochemistry characterizations, including polarization curve measurements, electrochemical impedance spectroscopy, or high frequency resistance measurements, are widely used to characterize the overall performance of PEMECs, and reflect some overall mass transport properties. But these characterizations can't describe