The use of micro-Raman imaging to measure  18 O tracer distribution in thermally grown zirconia scales

Guérain, Mathieu; Mermoux, Michel; Duriez, Christian

doi:10.1016/j.corsci.2015.05.020

Cited by 14 publications

(25 citation statements)

References 46 publications

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“…Briefly, the particular monoclinic ZrO 2 line, peaking at about 475 cm -1 when no 18 O is incorporated in the m-ZrO 2 oxygen sub-lattice, intense and isolated from the other lines, was used to extract the 18 O content in zirconia scales. As shown in [22], the line downshift versus the 18 O content was strong, estimated and measured to about 0.27 cm -1 / 18 O at.%. As shown by [22], stress and alloying effects may also modify the position of this particular Raman line.…”

Section: O Concentration Determination Using Raman Spectroscopymentioning

confidence: 76%

“…As shown in [22], the line downshift versus the 18 O content was strong, estimated and measured to about 0.27 cm -1 / 18 O at.%. As shown by [22], stress and alloying effects may also modify the position of this particular Raman line. However, these effects are small compared to the main isotopic effects.…”

Section: O Concentration Determination Using Raman Spectroscopymentioning

confidence: 76%

“…They were examined with a point spacing of 1 µm or less, if necessary. The whole procedure to extract 18 O profiles or maps from Raman mapping experiments has already been detailed in [19,22]. Briefly, the particular monoclinic ZrO 2 line, peaking at about 475 cm -1 when no 18 O is incorporated in the m-ZrO 2 oxygen sub-lattice, intense and isolated from the other lines, was used to extract the 18 O content in zirconia scales.…”

Section: O Concentration Determination Using Raman Spectroscopymentioning

confidence: 99%

“…The tests conducted on bare Zy-4 samples are probably the simplest to interpret, because, for rather low exposition times, they minimize the effects of isotopic exchange within the zirconia grains. Indeed, two-stage oxidation measurements made it possible to highlight two different oxygen diffusion paths, grains and grain boundaries [22]. They also strongly suggest a preferential diffusion path along the grain boundaries.…”

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confidence: 95%

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Experimental study of oxidation in oxygen, nitrogen and steam mixtures at 850∘C of pre-oxidized Zircaloy-4

Gestin

Mermoux

Coindreau

et al. 2019

Journal of Nuclear Materials

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HAL is a multidisciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

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Section: O Concentration Determination Using Raman Spectroscopymentioning

confidence: 76%

Section: O Concentration Determination Using Raman Spectroscopymentioning

confidence: 76%

Section: O Concentration Determination Using Raman Spectroscopymentioning

confidence: 99%

mentioning

confidence: 95%

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Experimental study of oxidation in oxygen, nitrogen and steam mixtures at 850∘C of pre-oxidized Zircaloy-4

Gestin

Mermoux

Coindreau

et al. 2019

Journal of Nuclear Materials

Self Cite

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“…Raman provides qualitative to semi-quantitative information on the material composition seen in oxides. The Raman spectra of common zirconium-based polymorphs have been extensively covered [16,17,20,[23][24][25][26]28,29,[40][41][42][43][44][45][46]. Distinct peaks have been well established for both monoclinic and tetragonal zirconia [14,18,22,24,26,40,[42][43][44].…”

Section: A42 Raman Spectroscopymentioning

confidence: 99%

Oxidation Behavior of Zirconium Alloys in Transient Conditions

Vandegrift¹

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Dr. Brian Jaques for teaching me leadership, work/life balance and for providing me with countless opportunities to grow as an engineer. Most importantly, Dr. Jaques taught me the value of learning something new every day, and I will carry that mindset with me for the rest of my career. I would like to thank my other committee members, Dr. Hurley and Dr. Parga for their support and guidance. I would also like to thank my peers at Boise State University for their support during this journey and for being excellent role models both in the lab and in life. Finally, I want to thank my friends and my family for pushing me to take every opportunity that has come my way. Without their continued support, this thesis would not exist.

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Isotope Exchange Raman Spectroscopy (IERS): A Novel Technique to Probe Physicochemical Processes In Situ

et al. 2023

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A novel in situ methodology for the direct study of mass‐transport properties in oxides with spatial and unprecedented time resolution, based on Raman spectroscopy coupled to isothermal isotope exchanges, is developed. Changes in the isotope concentration, resulting in a Raman frequency shift, can be followed in real time, which is not accessible by conventional methods, enabling complementary insights for the study of ion‐transport properties of electrode and electrolyte materials for advanced solid‐state electrochemical devices. The proof of concept and strengths of isotope exchange Raman spectroscopy (IERS) is demonstrated by studying the oxygen isotope back‐exchange in gadolinium‐doped ceria (CGO) thin films. Resulting oxygen self‐diffusion and surface exchange coefficients are compared to conventional time‐of‐flight secondary‐ion mass spectrometry (ToF‐SIMS) characterization and literature values, showing good agreement, while at the same time providing additional insight, challenging established assumptions. IERS captivates through its rapidity, simple setup, non‐destructive nature, cost effectiveness, and versatile fields of application and thus can readily be integrated as new standard tool for in situ and operando characterization in many laboratories worldwide. The applicability of this method is expected to consolidate the understanding of elementary physicochemical processes and impact various emerging fields including solid oxide cells, battery research, and beyond.

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The use of micro-Raman imaging to measure 18 O tracer distribution in thermally grown zirconia scales

Cited by 14 publications

References 46 publications

Experimental study of oxidation in oxygen, nitrogen and steam mixtures at 850∘C of pre-oxidized Zircaloy-4

Experimental study of oxidation in oxygen, nitrogen and steam mixtures at 850∘C of pre-oxidized Zircaloy-4

Oxidation Behavior of Zirconium Alloys in Transient Conditions

Isotope Exchange Raman Spectroscopy (IERS): A Novel Technique to Probe Physicochemical Processes In Situ

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