We present Hubble Space Telescope (HST) observations of the nearby (z= 0.023), very massive, highly rotating (488.4±12.5 km s −1 ) hybrid (S0-Sa) galaxy UGC 12591, along with observations taken at other wavelengths from UV to FIR. Deep HST data of the galaxy in V, I and H bands is used to disentangle its bulge and disk components. The surface brightness distributions show a dominance of the bulge component over the disk with H-band bulge-to-disc luminosity ratio ∼ 69%. From spectral energy distribution (SED) fitting, we find an extremely low global star formation rate (SFR) of ∼ 0.1 − 0.2M y −1 , which is unusually low for this galaxy's huge stellar mass (M ★ ∼ 1.6 × 10 11 M ), that implies a strong quenching of it's SFR. For at least past 10 8 years the galaxy has remained in the quiescent state as a sterile, 'red and dead' galaxy. The fraction of total infra-red dust luminosity contributed by the ISM dust is as high as ∼ 90%, with total dust luminosity L dust = (0.5 − 3.5) × 10 10 L , dominated by cold dust at equilibrium temperature T C ≈ 15K. UGC 12591 is found host to a super massive black hole (SMBH) of mass 6.18 × 10 8 M which at the present moment is quiescent, i.e., neither we see large (> 1kpc) radio jets nor is the black hole contributing significantly to the mid-IR SED, ruling out the presence of strong radiative feedback from a bright AGN. We have obtained a detailed census of all observable baryons in this galaxy. The star formation efficiency is very low (∼ 0.02 − 0.06) and within a virial radius the galaxy has a total observed baryonic mass of 6.87 × 10 11 M , amounting to a baryonic deficiency of ∼ 80% relative to the cosmological mean. A small fraction of these cosmic baryons reside in a warm/hot circum-galactic halo phase, while the majority of baryons are still not observable. We have discussed various astrophysical scenarios for explaining its unusual physical properties. Our work is a major step forward in understanding the assembly history of such extremely massive, isolated galaxies.