Recent high precision 142 Nd isotope measurements showed that global silicate differentiation may have occurred as early as 30-75 Myr after the Solar System formation [Bennett V, et al. (2007) Science 318:1907-1910. This time scale is almost contemporaneous with Earth's core formation at ∼30 Myr [Yin Q, et al. (2002) 142 Nd anomalies, all have a homogeneous W isotopic composition, which is ∼2ε-unit more radiogenic than the chondritic value. By using a 3-stage model calculation that describes the isotopic evolution in chondritic reservoir and core segregation, as well as silicate differentiation, we show that the W isotopic composition of terrestrial samples provides the most stringent time constraint for early core formation (27.5-38 Myr) followed by early terrestrial silicate differentiation that is consistent with the terrestrial 142 Nd anomalies.hafnium | tungsten | hidden reservoir | Hawaii | Iceland S hort-lived chronometers provide evidence for the rapid differentiation of planet Earth. In particular, 182 Hf-182 W (T 1∕2 ¼ 8.9 Myr) and 146 Sm-142 Nd (T 1∕2 ¼ 103 Myr) have been used to constrain the age of core formation (1, 2) and of silicate differentiation (3-7), respectively. All terrestrial rocks analyzed so far are characterized by 182 W∕ 184 W ratios that are ∼2ε-unit (see Table 1 caption for definition) higher than those of chondrites, which is commonly interpreted as evidence for early metal-silicate segregation and core formation (1, 2). Terrestrial rocks are also characterized by ∼0.2ε excess of 142 Nd∕ 144 Nd relative to chondrites (3). This excess has been interpreted as evidence for early global differentiation of the silicate Earth during the first 30-75 Myr of the Solar System, where the resulting enriched silicate reservoir is permanently stored at the base of the lowermost mantle (3), Hadean crust (8), or in the roots of cratons (9) (see SI Text for comments on alternative theories).Whereas tungsten is a moderately siderophile element, it is also highly incompatible during silicate partial melting; in fact, W, U, and Th all have similar partition coefficients (10, 11). In contrast, Hf, which is a lithophile element, is only moderately incompatible during silicate partial melting (11). Consequently, W is strongly fractionated from Hf during silicate melting events (12), resulting in oceanic and continental crust that is enriched in W (∼400 and ∼1;000 ppb, respectively) relative to the mantle (∼16 ppb) (12, 13). Therefore, mantle differentiation/melting events that occurred early enough in Earth's history (35-70 Myr), as constrained by 142 Nd data, should fractionate Hf/W ratios and result in ε 182 W anomalies with time. The ∼2ε 182 W anomalies observed between terrestrial rocks and chondrites (refs. 1 and 2 and this work) should, therefore, be attributed to the collective effects of both silicate melting (crust/mantle differentiation), as well as silicate/metal fractionation (core/mantle differentiation), and not solely because of the silicate/metal fractionation as previously thought ...