Theoretical and Experimental Aspects of the Reinforcement of Thermoplastics by Liquid Crystalline Polymers

Claßen, S.; Gallenkamp, U.; Wolf, M.; Wendorff, Joachim H.

doi:10.1007/978-94-009-0767-6_28

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“…Lattice calculations lead to the prediction that rigid cross-shaped or star-shaped multipodes composed of linear rigid branches and a rigid central core should be much more soluble both in organic solvents and in polymers than rigid rods of similar molecular weight [1,2]. These differences result purely from entropic contributions.…”

Section: Introductionmentioning

confidence: 99%

Rigid star-shaped adamantane multipodes

et al. 1998

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The synthesis of star‐shaped adamantane multipodes with rigid branches based on p‐hydroxybenzoic acid is reported. These multipodes are able to crystallize but can also be obtained in the glassy state. They are soluble in various low molar mass organic solvents, in fact, much better than linear rigid molecules of similar length, and they are miscible in polymer matrices up to concentrations of 30 wt%. The multipodes were found to influence the dielectric and mechanical properties of the polymers significantly.

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Section: Introductionmentioning

confidence: 99%