By combining microscopy investigation, light-beam induced current (LBIC), microphotoluminescence (µ-PL), and micro-electroluminescence (µ-EL) characterization, we investigate the electrical and optical properties of V-pits and trench-like defects in highperiodicity InGaN/GaN multiple quantum wells (MQWs) solar cells. Experimental measurements indicate that V-pits and their complexes are preferential conductive paths under reverse and forward bias. Spectral analysis shows a redshifted wavelength contribution, with respect to MQWs emission peak wavelength, in presence of agglomerates of V-pits surrounded by trench-like defects. The intensity of the redshifted wavelength contribution Manuscript