The HPALD formation in the OH-initiated isoprene oxidation has been revisited. Vibrationally hot peroxy radicals from O2 addition in the α-position of Z,Z′-OH-allyl radicals decompose in a chemically activated manner, efficiently yielding δ-HPALDs.
The HPALD formation in the OH-initiated isoprene oxidation has been revisited. Vibrationally hot peroxy radicals from O2 addition in the α-position of Z,Z′-OH-allyl radicals decompose in a chemically activated manner, efficiently yielding δ-HPALDs.
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