Theory and applications of ion-selective electrodes part 4

Koryta, J.

doi:10.1016/s0003-2670(01)93983-2

Cited by 53 publications

(8 citation statements)

References 442 publications

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“…(3) with Eqs. (4)- (8) can be rewritten in the same form as the semiempirical Nicolsky-Eisenman equation [22]:…”

Section: Effect Of Interfering Ionsmentioning

confidence: 99%

“…Even now, after a variety of analytical methods have been developed for sensing ions, PVC membrane ISEs hold an important position in practical ion analysis, particularly in clinical analysis [3] (e.g., the determination of Na + /K + /Cl À in blood serum). So far, a tremendous number of PVC membrane ISEs have been developed for many ions [2][3][4][5][6][7][8][9][10][11][12], however the design of these ISEs is usually due to screening or trial-and-error.…”

Section: Introductionmentioning

confidence: 99%

“…This concentration dependence can be elucidated in terms of the concentration ratio of the interfering and primary ions in W. Note that the MP is given by the function of the ratio (c W K2 =c W K1 ); see Eqs. (6)- (8).…”

mentioning

confidence: 99%

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Interpretation of the potential response of PVC membrane ion-selective electrodes based on the mixed potential theory

Osakai

Sato

Imoto

et al. 2012

Journal of Electroanalytical Chemistry

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“…(3) with Eqs. (4)- (8) can be rewritten in the same form as the semiempirical Nicolsky-Eisenman equation [22]:…”

Section: Effect Of Interfering Ionsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Interpretation of the potential response of PVC membrane ion-selective electrodes based on the mixed potential theory

Osakai

Sato

Imoto

et al. 2012

Journal of Electroanalytical Chemistry

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“…This review describes individual carrier-based ISEs and bulk optodes, ordered according to the analyte for which they have been developed. Many reviews on ISEs have been written, − selected topics have been covered in the journal Ion-Selective Electrode Reviews , and a little-known electronic database summarizes a large number of data on potentiometric sensors (for a first-time user some knowledge of Japanese seems necessary for utilizing this database) . A more readily accessible data collection in book form tabulated selectivity data, detection limits, linear ranges, response slopes, and lifetimes of many solid and liquid membrane ISEs up to 1988…”

Section: Introductionmentioning

confidence: 99%

Carrier-Based Ion-Selective Electrodes and Bulk Optodes. 2. Ionophores for Potentiometric and Optical Sensors

1998

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and 1991, respectively. He has been working in the field of chemical sensors since 1970. Further topics of his interest are spectroscopic databases, automatic spectra interpretation, and modeling of structure−property relationships. He has published over 180 papers and 7 books. Current activities in the fields of chemical sensors and computer-aided analytical chemistry are documented on the web page http://www/ceac.ethz.ch/pretsch/. His e-mail address is pretsch@ org.chem.ethz.ch.

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“…A large number of anion-selective liquid membrane electrodes based on classical ion exchangers such as quaternary ammonium salts, phosphonium salts, complexes of 0-phenanthroline, and of other complexing agents have been described (1)(2)(3)(4). Electrodes have been proposed for the analysis of Cl-(5-9), NO, (3,9, IO), SCN-(11-13) and other inorganic as well as organic anions.…”

mentioning

confidence: 99%

Tin organic compounds as neutral carriers for anion selective electrodes

Wuthier¹,

Pham²,

Zuend³

et al. 1984

Anal. Chem.

146

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Trl-n-octyltln chlorlde acts as a neutral carrler for anlons. Llquld membranes contalnlng thls carrler, ( R ,R )-2,3dlmeth-oxysuccinic acld bls( 1-butylpentyl) ester as plastlclzer, and poly(vlny1 chlorlde) as membrane malrlx show selectlvlly patterns whlch are not In accordance with the sequence obtained for classlcal anlon exchangers. These neutral carrler membranes dlsplay Nernstian electrode functlons for dlfferenl anlons In the I O 9 M to IO-' M concentratlon range. NMR and vapor pressure osmometry studles lndlcate an lnteractlon of the tln organlc compound wlth the chlorlde anlon. The expected mlgrallon of the tin organic compound In the dlrectlon of the anode is demonstrated with an electrodlalytlc transport experlment.A large number of anion-selective liquid membrane electrodes based on classical ion exchangers such as quaternary ammonium salts, phosphonium salts, complexes of 0-phenanthroline, and of other complexing agents have been described (1-4). Electrodes have been proposed for the analysis of Cl-(5-9), NO, (3,9, IO), SCN-(11-13) and other inorganic as well as organic anions. For electrodes based on tetraalkylammonium salts, 35 different detectable anions have been mentioned in ref 1. Usually all these electrodes exhibit roughly the same selectivity sequence with a preference of lipophilic and a rejection of hydrophilic anions (14, 15). In these cases, the free energy of transfer of the anions from the aqueous sample phase to the membrane phase-and therefore the membrane selectivity-is controlled by the free energy of hydration of these ions (4,16-20). This is in contrast to neutral carrier based systems for cations, where the ion selectivity highly depends on the free energy of the interaction of the ions with the ligand (14,21). In the latter case, a wide variety of ion selectivities is made accessible (22).Tin organic compounds have been used as components in anion selective electrodes with response t o C1-(23), HAs0,2-IH2As04-(N), NO, (W), and other species. Although tripropyl tin chloride (26) and other triorgano tin compounds (27) have been found to influence anion transport, it has not yet been properly proved that such tin organic compounds may act as neutral carriers for anions. In this paper, we show that trioctyltin chloride displays anion carrier properties if incorporated in solvent polymeric membranes. EXPERIMENTAL SECTIONCell Assemblies for EMF Studies. For all EMF measurements, cells of the following type were used: Hg, Hg2C12; KC1 (satd)llM LiOAclsample solution llmembrane 110.01 M NaC1; AgC1, Ag The external reference electrode was a double junction saturated calomel electrode with a ceramic diaphragm (for details see ref 28). Measurements were performed with four different membranes of the following compositions: (a) 6 wt % methyltri-ndodecylammonium chloride (MTDDACl), 65 wt % di-n-butyl phthalate (DBP), 29 wt % poly(viny1 chloride) (PVC); (b) 3 wt % MTDDACI, 49 wt % (R,R)-2,3-dimethoxysuccinic acid bis(1-butylpentyl) ester (DMSNE), 48 wt % PVC; (c) 3 wt % tri-noctyltin chloride...

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Theory and applications of ion-selective electrodes part 4

Cited by 53 publications

References 442 publications

Interpretation of the potential response of PVC membrane ion-selective electrodes based on the mixed potential theory

Interpretation of the potential response of PVC membrane ion-selective electrodes based on the mixed potential theory

Carrier-Based Ion-Selective Electrodes and Bulk Optodes. 2. Ionophores for Potentiometric and Optical Sensors

Tin organic compounds as neutral carriers for anion selective electrodes

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