Thermal decomposition of MCl2[M = Co(II), Ni(II), Cu(II)] in sodium nitrate—potassium nitrate eutectic melt

Singh, N. B.; Pandey, S.P.

doi:10.1016/0040-6031(83)80094-x

Cited by 11 publications

(2 citation statements)

References 5 publications

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“…Another concept is that metal ions act as Lux-Flood acids (oxide ion acceptors) in nitrate melts (34,35). In many instances, especially at the higher temperatures, metal ions can react directly with the nitrate melt to form the metal oxide even without the aid of any electrochemical reaction (18,36). In many instances, especially at the higher temperatures, metal ions can react directly with the nitrate melt to form the metal oxide even without the aid of any electrochemical reaction (18,36).…”

Section: Discussionmentioning

confidence: 99%

“…These concepts are interrelated in that some type of interaction of the metal ion with the nitrate or perchlorate ligand facilitates its reduction to form the metal oxide. In many instances, especially at the higher temperatures, metal ions can react directly with the nitrate melt to form the metal oxide even without the aid of any electrochemical reaction (18,36).…”

Section: Discussionmentioning

confidence: 99%

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Problems Associated with the Electrochemical Reduction of Metal Ions in LiNO3 ‐ KNO 3 and LiClO4 ‐ KClO4 Melts: The Reduction of Nitrato and Perchlorato Complexes

Miles

McManis

Fletcher

1987

J. Electrochem. Soc.

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Electrochemical studies of Ag § T1 § Cd + § Pb + § Zn ++, and In +++ metal ions on platinum electrodes in molten LiNO3-KNO3 show that only silver ions are readily reduced to the metal within the electrostability region of the melt. The other metal ions form nitrato complexes that are reduced directly to the metal oxide at potentials less negative than solvent reduction. For divalent metal ions, these reactions can be represented by (MONO2) + + 2e----, MO § NO2 . Scission of the O--N bond likely occurs in the first electron transfer step. The atomic absorbance analysis of a mercury cathode used in the exhaustive electrolysis of Cd § ions provided substantial evidence that the deposition of cadmium metal does not occur in the LiNO3-KNO3 melt. Investigations of Cd and Zn metals and amalgams show that the much faster M § ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 128.122.253.212 Downloaded on 2015-05-14 to IP Vol. 134, No. 3 NITRATE AND PERCHLORATE MELTS 615

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Section: Discussionmentioning

confidence: 99%

Section: Discussionmentioning

confidence: 99%

Problems Associated with the Electrochemical Reduction of Metal Ions in LiNO3 ‐ KNO 3 and LiClO4 ‐ KClO4 Melts: The Reduction of Nitrato and Perchlorato Complexes

Miles

McManis

Fletcher

1987

J. Electrochem. Soc.

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Molten Salt‐Assisted Synthesis of Catalysts for Energy Conversion

Chen,

2024

Advanced Materials

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A breakthrough in manufacturing procedures often enables people to obtain the desired functional materials. For the field of energy conversion, designing and constructing catalysts with high cost‐effectiveness is urgently needed for commercial requirements. Herein, the molten salt‐assisted synthesis (MSAS) strategy is emphasized, which combines the advantages of traditional solid and liquid phase synthesis of catalysts. It not only provides sufficient kinetic accessibility, but effectively controls the size, morphology, and crystal plane features of the product, thus possessing promising application prospects. Specifically, the selection and role of the molten salt system, as well as the mechanism of molten salt assistance are analyzed in depth. Then, the creation of the catalyst by the MSAS and the electrochemical energy conversion related application are introduced in detail. Finally, the key problems and countermeasures faced in breakthroughs are discussed and look forward to the future. Undoubtedly, this systematical review and insights here will promote the comprehensive understanding of the MSAS and further stimulate the generation of new and high efficiency catalysts.

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Cyclic voltammetric studies of nitrato complexes of various metal ions in molten LiNO3 + KNO3 at 180°C

Miles

Fletcher

1987

Journal of Electroanalytical Chemistry and Interfacial Electroc

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Thermal decomposition of MCl2[M = Co(II), Ni(II), Cu(II)] in sodium nitrate—potassium nitrate eutectic melt

Cited by 11 publications

References 5 publications

Problems Associated with the Electrochemical Reduction of Metal Ions in LiNO3 ‐ KNO 3 and LiClO4 ‐ KClO4 Melts: The Reduction of Nitrato and Perchlorato Complexes

Problems Associated with the Electrochemical Reduction of Metal Ions in LiNO3 ‐ KNO 3 and LiClO4 ‐ KClO4 Melts: The Reduction of Nitrato and Perchlorato Complexes

Molten Salt‐Assisted Synthesis of Catalysts for Energy Conversion

Cyclic voltammetric studies of nitrato complexes of various metal ions in molten LiNO3 + KNO3 at 180°C

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