2020
DOI: 10.1039/c9cp06867h
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Thermal decomposition of mixed calcium oxalate hydrates – kinetic deconvolution of complex heterogeneous processes

Abstract: Whereas thermogravimetry monitors only a single-step CaOx decomposition reaction, DSC in addition reveals the complex competing CO oxidation kinetics.

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Cited by 13 publications
(9 citation statements)
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“…This enables to identify and quantify the volatile compounds CO and CO 2 evolving during this step, and, consequently, the contribution of the thermal effects of the indicated reaction within the global thermal balance of this II° event. These outcomes agree with the conclusions pointed out in an in‐depth analysis of the thermal behavior of the COM recently published 34 …”
Section: Introductionsupporting
confidence: 92%
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“…This enables to identify and quantify the volatile compounds CO and CO 2 evolving during this step, and, consequently, the contribution of the thermal effects of the indicated reaction within the global thermal balance of this II° event. These outcomes agree with the conclusions pointed out in an in‐depth analysis of the thermal behavior of the COM recently published 34 …”
Section: Introductionsupporting
confidence: 92%
“…The detection of CO 2 during the thermal decomposition of calcium oxalate unequivocally indicates the occurrence of a further secondary reaction during the second step. To the authors knowledge, this CO 2 formation, mentioned in some papers 30,34,55,56 is always led back to a partial (or total) oxidation of CO, yielded from reaction 2, following the stoichiometry: CO+1/2·normalO2CnormalO2…”
Section: Investigation Of the Secondary Reaction In The Second Therma...mentioning
confidence: 99%
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