This paper presents an ultra-high-frequency (UHF) passive sense tag for electrical grid and substation thermal monitoring, with emphasis on the tag system optimization and the design of a low power embedded temperature sensor. The designed tag achieves a sensitivity of −12.3 dBm under active temperature monitoring operation, which is the state of the art among existing UHF passive temperature sense tag products. The sensing inaccuracy of the tag is ±2.5 • C (3σ) from −25 to 120 • C after a low-cost wireless single-point trim. An antimetal ceramic-packaged tag was tested by attaching to a ring main unit in the substation and complete tag system demonstrated robust wireless operation with a sensing distance of 3.5 m. The combination of batteryless and wireless operation, high sensitivity, wide sensing range, and small incident-power-dependent error (±0.2 • C) makes this tag suitable for the target applications. Index Terms-Antimetal antenna, CMOS temperature sensor, grid thermal monitoring, radio-frequency identification tag (RFID) temperature sense tag, relaxation clock generator, ultra-high-frequency (UHF) RFID.