A X B X t r r r r ), where r A , r B , and r X stand for the ionic radii of A, B, and X, respectively. For cubic or pseudo-cubic crystal structures, the ideal value for t is 1 or a wave between 0.813 and 1.107; tolerance values that deviate significantly from 1 lead to warping and destruction of the structure. [25,26] As reported by Shannon, [27] the ionic radii for Pb 2+ and Eu 2+ are 1.19 and 1.17 Å, respectively. The similarity in size between lead and europium suggests the potential to replace lead with the more environmental-friendly europium. In this vein, many CsEuX n (X = Cl, I) structures have been reported, including CsEuCl 3 , [28,29] CsEu 2 I 5 , [30] and CsEuI 3 . [30,31] Preparation Lead-based perovskite nanocrystals (NCs) are promising candidates for use in lighting and display applications; however, the toxicity of lead is one critical issue that needs to be solved for its commercialization. Consequently, less toxic tin and bismuth-based perovskite NCs have been developed, but these materials exhibit low photoluminescence quantum yields (PLQYs) and large full width at half maximum (FWHM) values. Due to their similarity in size for Eu 2+ and Pb 2+ , the more environmental-friendly europium shows the potential to replace lead. Herein, the synthesis of Eu 2+ doped CsBr NCs with an average size of 51.5 nm via a facile hot-injection method is reported. The prepared CsBr:Eu 2+ NCs exhibit an emission peak at 440 nm with an FWHM of 31 nm and PLQY up to 32.8%, which is persistent for at least 60 d. Moreover, the size and FWHM of CsBr:Eu 2+ NCs can be tuned to 18.9 and 29 nm, respectively, by co-doping of Ca 2+ ions into the NCs. It is also demonstrated that the prepared CsBr:Eu 2+ NCs can be employed as efficient color conversion materials for fabricating white light-emitting diodes.