Thermal studies on acetylenedicarboxylic acid compounds of iron(II), cobalt(II), nickel(II), copper(II) and zinc(II)

Allan, J.R.; Beaumont, Paul C.; Macindoe, L.; Milburn, G. H. W.; Werninck, A. R.

doi:10.1016/0040-6031(87)88100-5

Cited by 7 publications

(2 citation statements)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The thermal behavior of 1 is also different from that observed in other complexes of H 2 ADC. , Indeed, we previously mentioned that the partially dehydrated solid 2 contains already stable radicals. Moreover, the solid-state polymerization process at 160 °C is only slightly exothermic and overcomes the drawback of the large exothermic effect which usually accompanies the solid-state polymerization reactions .…”

Section: Resultsmentioning

confidence: 64%

Crystal Structure and Solid-State Reactivity of a Cd(II) Polymeric Complex with Acetylenedicarboxylic Acid

et al. 2003

View full text Add to dashboard Cite

The novel one-dimensional coordination polymer [Cd(ADC)(H 2 O) 3 ] H 2 O, where ADC 2-) acetylenedicarboxylate dianion, was synthesized and characterized by single-crystal X-ray diffraction. The titled compound crystallizes in the monoclinic system, P2 1 /n, a ) 6.908(1) Å, b ) 7.946(1) Å, c ) 16.390(1) Å, β ) 100.21(1)°, V ) 885.4(2) Å 3 , and Z ) 4. The structure is made up of metal-organic chains linked by hydrogen bonds to form channels along the b axis. The carbon-carbon triple bonds are in close proximity (3.27 Å) along the a axis. This induces, upon heating, polymerization with formation of conjugated polycarboxylic chains. Detailed EPR studies have been performed in order to understand the polymerization process.

show abstract

Section: Resultsmentioning

confidence: 64%

Crystal Structure and Solid-State Reactivity of a Cd(II) Polymeric Complex with Acetylenedicarboxylic Acid

et al. 2003

View full text Add to dashboard Cite

show abstract

“…1(a) and (b)). 30 Its 13 C NMR spectrum shows two peaks at about 156 ppm and 76 ppm, corresponding to the carbon atom of the carboxyl group and the acetylenic part, respectively (Fig. 1(c)).…”

Section: Linear Organic Linkers In Coordination Polymers and Metal-or...mentioning

confidence: 99%

Acetylenedicarboxylate as a linker in the engineering of coordination polymers and metal–organic frameworks: challenges and potential

et al. 2022

View full text Add to dashboard Cite

show abstract

Metal Acetylene Dicarboxlylates as Catalyst for Printable Low Temperature Carbon Precursors

Otto,

Gellrich,

Bräuniger

et al. 2024

Eur J Inorg Chem

View full text Add to dashboard Cite

The synthesis of various metal acetylene dicarboxylates (MxADC, M = Cu, Ag, Fe, Co, Ni) via new methods are reported. The previously unknown crystal structures for Ag2ADC and FeADC are presented. The behaviour of the different metal dicarboxylates and their role as graphitization catalysts in a printable highly energetic carbon precursor is investigated in detail. Despite the copper compound has the lowest decomposition temperature of all studied acetylene dicarboxylates and is significantly enhancing the conductivity of carbon thin films obtained at low pyrolysis temperatures, the catalytic effect of cobalt and iron on graphitizing carbon results in a superior conductivity in carbon thin films pyrolyzed at lower temperatures down to 600°C. The newly designed precursors are demonstrated to produce micro‐supercapacitors with a 3D‐piezoelectric inkjet technique at low pyrolysis temperature.

show abstract

Thermal studies on acetylenedicarboxylic acid compounds of iron(II), cobalt(II), nickel(II), copper(II) and zinc(II)

Cited by 7 publications

References 6 publications

Crystal Structure and Solid-State Reactivity of a Cd(II) Polymeric Complex with Acetylenedicarboxylic Acid

Crystal Structure and Solid-State Reactivity of a Cd(II) Polymeric Complex with Acetylenedicarboxylic Acid

Acetylenedicarboxylate as a linker in the engineering of coordination polymers and metal–organic frameworks: challenges and potential

Metal Acetylene Dicarboxlylates as Catalyst for Printable Low Temperature Carbon Precursors

Contact Info

Product

Resources

About