2018
DOI: 10.1039/c7cp04835a
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Thermally reversible nanoparticle gels with tuneable porosity showing structural colour

Abstract: We present colloidal gels formed from dispersions of PEG- and PEG+DNA-coated silica nanoparticles showing structural colour. The PEG- and PEG+DNA-coated silica colloids are functionalized using exclusively covalent bonds in aqueous conditions. Both sets of colloids self-assemble into thermally-reversible colloidal gels with porosity that can be tuned by changing the colloid volume fraction, although the interaction potentials of the colloids in the two systems are different. Confocal microscopy and image analy… Show more

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Cited by 4 publications
(2 citation statements)
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“…At the structural level these terms are used to describe whether the nanoparticles show a tendency to cluster because of weak physical interactions that can be reversed in biological preparations or by strong forces where the clustering is practically irreversible. 17 Reversible clustering and "selfassembly" can be controlled thermally, 18 chemically, 19 or by light. 20 The concept of reversibility can also be extended to the description of how different nanoparticles bind to biological substrates.…”
Section: Nanomaterialsmentioning
confidence: 99%
“…At the structural level these terms are used to describe whether the nanoparticles show a tendency to cluster because of weak physical interactions that can be reversed in biological preparations or by strong forces where the clustering is practically irreversible. 17 Reversible clustering and "selfassembly" can be controlled thermally, 18 chemically, 19 or by light. 20 The concept of reversibility can also be extended to the description of how different nanoparticles bind to biological substrates.…”
Section: Nanomaterialsmentioning
confidence: 99%
“…In recent years, stimuli-responsive structural colors have been paid much attention. [21][22][23][24][25][26][27][28][29][30][31][32] Inspired by the ability to change the skin color during male contests or courtship of panther chameleons, some strategies have been developed to adjust the periodic structures aer their preparation. Yang et al prepared photonic crystals in shape memory polymers (SMPs) by selfassembling silica particles in a polymer matrix and the subsequent removal of silica colloids by wet etching.…”
Section: Introductionmentioning
confidence: 99%