Thermally stimulated current (TSC) measurement is widely used in a variety of research fields, i.e., physics, electronics, electrical engineering, chemistry, ceramics, biology, etc. TSC is short circuit current and it flows due to displacement of charges in samples during heating. The TSC measurement is very simple, but TSC curves give much important information on charge behaviors. In 1970's, TSC measurement made a great contribution to the development of electrical insulation engineering, to the development of semiconductor device technology, and so forth. Accordingly, TSC experimental technique and its analytical method had advanced. On the other hand, during the past several ten years, many new molecules and advanced functional materials have been discovered and developed. Along with this situation, TSC measurement has attracted much attention in industries and in academic laboratories as a way for characterizing discovered new materials and devices. This review reports the latest research trend in TSC method for development of Materials and Devices in Japan.