Polycrystalline silicon (poly-Si) thin films with large grains and low defect density are promising materials for thin film transistors (TFTs) for use as the pixel switching elements as well as for use as the driving elements in active matrix liquid crystal displays. For these applications it is necessary to fabricate TFTs on glass substrates and, therefore, a number of low temperature processes are currently being explored. 1,2 Laser and solid-phase crystallization of amorphous silicon (a-Si) precursors which are prepared from lowpressure chemical vapor deposition (LPCVD), sputtering, or plasma-enhanced chemical vapor deposition (PECVD) as well as the direct deposition of poly-Si are some promising approaches. 3,4 The solid-phase crystallization (SPC) approach by furnace annealing or rapid thermal annealing (RTA) has several advantages over other poly-Si fabrication processes. These advantages include smoother surfaces, better uniformity, and, when compared to laser crystallized poly-Si, higher throughput. 5 In this paper, we first report on the SPC of PECVD a-Si:H films deposited on either bare glass or silicon nitride (SiN x ) coated glass substrates. Our investigation utilized precursor films deposited at a series of temperatures. In order to examine SPC kinetics in detail, we used conventional furnace annealing at 600ЊC in N 2 ambient for the SPC step. Since the drive is to lower temperature processing and since silicon nitride (SiN x ) can be used as an effective diffusion barrier layer, 6,7 it is important for the understanding of the low temperature production of TFTs to investigate the effects of precursor deposition and substrate coating on a-Si:H crystallization and on microstructural qualities of the resulting poly-Si thin films. Upon the completion of detailed material characterization of the deposited a-Si:H films and their corresponding crystallized poly-Si, we then fabricated n-channel poly-Si TFTs on these same films. Transistor parameters were measured, and transistor characteristics were correlated with material properties of the poly-Si films.
ExperimentalPolycrystalline silicon material preparation and characterization.-The a-Si:H films investigated in this study were PECVD deposited from H 2 -diluted silane (SiH 4 ) gas (4:1) in an Applied Kamatsu system. These a-Si:H films were deposited on either bare Corning 7059 glass substrates or Corning 7059 glass substrates coated with 100 nm thick silicon nitride. The SiN x layers were also deposited by PECVD in the same system from silane, ammonia (NH 3 ), and nitrogen (N 2 ) gases without exposure to air. For a-Si:H films on nitride-coated substrates the a-Si:H layers were deposited following the deposition of SiN x layers. Before loading in the PECVD tool, the glass substrates were cleaned using detergent and DI water then dried in hot air. The substrate temperature during deposition was varied between 150 and 320ЊC, and the deposition rate was kept constant at 10 Å/s. The thicknesses of the deposited a-Si:H films were of the order of 1000 Å. The...