Thermodynamic properties of (acetone+methanol+2-butanol ) atT=298.15K

Orge, B.; Iglesias, M.; Marino, G.; Tojo, J.

doi:10.1006/jcht.1998.0468

Cited by 14 publications

(6 citation statements)

References 16 publications

(26 reference statements)

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“…Quantitative information on solute-solvent intermolecular interactions can be obtained from the limiting excess partial molar volumes, (V E;1 i ), of each component in the mixture [18][19][20]. We have, thus, used the Redlich-Kister least squares fitting correlation coefficients, A k , (Table 3) to obtain values of the limiting excess partial molar volumes for n-alkane, (V E;1 1 ) and MO, (V E;1 2 ) components in each binary system using the relations below [18][19][20];…”

Section: Resultsmentioning

confidence: 99%

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C₆–C₉) n‐Alkanes at 298.15 and Atmospheric Pressure

Yeboah

Oathotse

Ddamba

2014

J Americ Oil Chem Soc

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Densities q, ultrasonic speeds u and dynamic viscosities g, of mixtures of morama, Tylosema esculentum, seed oil with n-hexane, n-heptane, n-octane and n-nonane were determined over the entire composition range at 298.15 K and atmospheric pressure. Excess molar volumes, V E m , excess molar free volumes V E f , deviations in isentropic compressibility, Dj s , deviations in ultrasonic speed, Du, deviations in viscosity, Dg, and the excess free energy of activation of viscous flow, DG* E , were calculated therefrom and correlated by the Redlich-Kister equation for each of the [morama seed oil ? (n-hexane or n-heptane or n-octane or n-nonane)] mixtures. The results have been discussed in terms of possible intermolecular interactions and structural effects.

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Section: Resultsmentioning

confidence: 99%

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C₆–C₉) n‐Alkanes at 298.15 and Atmospheric Pressure

Yeboah

Oathotse

Ddamba

2014

J Americ Oil Chem Soc

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“…The values for V 1 m;2 ðEt 2 NH þ 2 Cl À Þ, at the other temperatures, were estimated assuming that (3), A k (cm 3 AE mol À1 ), 4th degree polynomial fits and A 0 k (cm 3 AE mol À1 ), 2nd degree polynomial fits, in the composition range 0 6 x 2 6 0.01 and corresponding standard deviations of the fits, r A (cm 3 AE mol À1 ) and r 0 A (cm 3 AE mol À1 ) for (water + DEA), from T = (278. 15 the expansion behaviour of ðEt 2 NH þ 2 OH À Þ would be similar to (Et 4 N + OH À ). The limiting partial molar isobaric expansions of Et 4 N + have been calculated based on data reported in reference [20].…”

Section: Excess Molar and Excess Partial Molar Volumesmentioning

confidence: 88%

“…The resulting expressions already used by various authors and ourselves [14][15][16] are given by equation (6) and (7) for, respectively, components 1 and 2…”

Section: Excess Molar and Excess Partial Molar Volumesmentioning

confidence: 99%

Volumetric study of (diethylamine+water) mixtures between (278.15 and 308.15) K

Lampreia

Dias

Mendonça

2004

The Journal of Chemical Thermodynamics

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“…(11) limiting excess values can be expressed in terms of the A k coefficients. The resulting expressions first obtained by Maham and co-workers 33 and also used by Orge et al, 34 are given in eqn. ( 13) and ( 14)…”

Section: Limiting Excess Partial Molar Isobaric Expansionsmentioning

confidence: 99%

Isobaric expansions and isentropic compressions of aqueous binary mixtures of 2-diethylaminoethanol from 283 to 303 K

Lampreia

Dias

Barbas

et al. 2003

Phys. Chem. Chem. Phys.

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Densities and ultrasound speeds were determined in aqueous binary mixtures of 2-diethylaminoethanol over the whole composition range at intervals of 5 K in the temperature range between 283 and 303 K. Thermal expansibility effects on this amphiphile/water mixture are analysed in terms of excess molar isobaric expansions E E P;m for the mixture and of excess apparent molar isobaric expansions E E P;f;i for both chemical substances in the mixture. Different strategies are used and discussed for obtaining limiting (infinite dilution) excess partial molar isobaric expansions. Compressibility effects are described in terms of excess molar isentropic compressions K E S;m and excess partial molar isentropic compressions K E S;i . The latter properties are analytically calculated from the fit of experimental K E S;m data to a Redlich-Kister equation. A method based on this equation yields limiting excess partial molar isentropic compressions. Additionally, excess ultrasound speeds u E are also examined. All these excess properties are referred to a thermodynamically defined ideal liquid mixture. Interesting insights into the mixing process are gained from the visual impact of plots showing the composition and temperature dependence of different excess molar thermodynamic properties. Comparison of expansibility-and compressibility-related quantities shows that these two types of thermodynamic properties probe different aspects of intermolecular and packing effects on the process of mixing amphiphiles and water.y Electronic supplementary information (ESI) available: Tables S1-S4. See

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Thermodynamic properties of (acetone+methanol+2-butanol ) atT=298.15K

Cited by 14 publications

References 16 publications

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C₆–C₉) n‐Alkanes at 298.15 and Atmospheric Pressure

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C₆–C₉) n‐Alkanes at 298.15 and Atmospheric Pressure

Volumetric study of (diethylamine+water) mixtures between (278.15 and 308.15) K

Isobaric expansions and isentropic compressions of aqueous binary mixtures of 2-diethylaminoethanol from 283 to 303 K

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Thermodynamic properties of (acetone+methanol+2-butanol ) atT=298.15K

Cited by 14 publications

References 16 publications

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C6–C9) n‐Alkanes at 298.15 and Atmospheric Pressure

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C6–C9) n‐Alkanes at 298.15 and Atmospheric Pressure

Volumetric study of (diethylamine+water) mixtures between (278.15 and 308.15) K

Isobaric expansions and isentropic compressions of aqueous binary mixtures of 2-diethylaminoethanol from 283 to 303 K

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Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C₆–C₉) n‐Alkanes at 298.15 and Atmospheric Pressure

Investigation of Some Physicochemical Properties of Mixtures of Morama Seed Oil with (C₆–C₉) n‐Alkanes at 298.15 and Atmospheric Pressure