Thermodynamic Properties of Aqueous Lithium Chloride Solutions. An Evaluation of the Gas Current Method for the Determination of the Thermodynamic Proper-ties of Aqueous Salt Solutions.

Johnson, Ernest F.; Molstad, M. C.

doi:10.1021/j150485a014

Cited by 33 publications

(12 citation statements)

References 5 publications

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“…We used data from the literature to establish interpolating equations for the differential enthalpy of dilution of aqueous solutions of lithium chloride [40,112] and calcium chloride [46,124]. The equations have the general form:…”

Section: Differential Enthalpy Of Dilutionmentioning

confidence: 99%

Properties of aqueous solutions of lithium and calcium chlorides: formulations for use in air conditioning equipment design

Conde¹

2004

International Journal of Thermal Sciences

721

225

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Section: Differential Enthalpy Of Dilutionmentioning

confidence: 99%

Properties of aqueous solutions of lithium and calcium chlorides: formulations for use in air conditioning equipment design

Conde¹

2004

International Journal of Thermal Sciences

721

225

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“…These data are in reasonable agreement with literature values, although they are difficult to compare owing to differences in temperature, concentration, impurities, or method. For instance, the water vapor pressure of LiCl has been reported by Johnson et al with 16.1 mbar at a concentration of 45.8 wt % (30 °C) using an indirect calorimetric method . All investigated ILs obtained a reduced or comparable water vapor pressure referring to LiCl as a benchmark.…”

Section: Resultsmentioning

confidence: 85%

“…For instance, the water vapor pressure of LiCl has been reported by Johnson et al with 16.1 mbar at a concentration of 45.8 wt % (30 °C) using an indirect calorimetric method. 56 All investigated ILs obtained a reduced or comparable water vapor pressure referring to LiCl as a benchmark. Compared to the halide-containing…”

Section: ■ Results and Discussionmentioning

confidence: 99%

Sorbent Properties of Halide-Free Ionic Liquids for Water and CO₂ Perfusion

Brünig

Maurer

Pietschnig

2017

ACS Sustainable Chem. Eng.

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Aqueous solutions of lithium halides are state-of-the-art sorbents in sorption-based heat pump and heat storage devices, with the drawbacks of high corrosivity and limited natural resources of lithium. Halide-free ILs could be well-suited alternative sorbents and have been explored with isothermal titration calorimetry showing superior thermochemical performance. Here, we have explored the performance of selected halide-free ILs in perfusion measurements monitoring the uptake of water vapor and CO2 from an air stream with well-defined flow and humidity as a model for open sorption processes. We have determined the saturation vapor pressure of water in the corresponding water–IL mixtures and moreover determined the diffusion coefficients of molecular species in binary [EMIM][Ac]–water mixtures via pulsed-field-gradient nuclear magnetic resonance (PFG NMR) measurements. These, together with variation of the absorption rates with calorimetric monitoring, indicate that diffusion is approximately 3 orders of magnitude faster than absorption and that the fast absorption process is not diffusion limited for [EMIM][Ac] in the used concentration range (D = 5.046 ± 0.021 × 10–11 m2/s; T = 25 °C). All measurements have been carried out in comparison to LiCl which corroborates the superior performance with regard to reducing water vapor pressure, heat of dilution, and absorption rate of acetate-based ILs and [EMIM][Ac], in particular.

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“…where, abs is the enthalpy of absorption (dilution) (J/kg), which is defined for the aqueous solution of lithium chloride as [19]: …”

Section: B Dehumidification Processmentioning

confidence: 99%

Analytical Study of a Heat Recovery/Desiccant Cooling System under Tunisian Climatic Conditions

Sabek¹,

Nasr²,

Chouikh³

et al. 2015

JOCET

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Abstract-The solar potential energy in Tunisia can be used like a principal factor for the operation of new technologies of air conditioning. Studies could be carried out like approaches of simulation, analyzes experimental or both unit. In this paper, we present an analytical solution of heat and mass transfer processes in regenerator and air conditioning system (ACS) cores of a heat recovery /desiccant cooling system (HRDCS) under Tunisia weather conditions. Simulations programs were carried out to test the principal components of the HRDC system. The results show that the coefficient of performance of system improves when we use the renewable energy for heating and cooling. This study is significant and effective to prove the efficiency of such HRDC systems in this country.

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Thermodynamic Properties of Aqueous Lithium Chloride Solutions. An Evaluation of the Gas Current Method for the Determination of the Thermodynamic Proper-ties of Aqueous Salt Solutions.

Cited by 33 publications

References 5 publications

Properties of aqueous solutions of lithium and calcium chlorides: formulations for use in air conditioning equipment design

Properties of aqueous solutions of lithium and calcium chlorides: formulations for use in air conditioning equipment design

Sorbent Properties of Halide-Free Ionic Liquids for Water and CO₂ Perfusion

Analytical Study of a Heat Recovery/Desiccant Cooling System under Tunisian Climatic Conditions

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Thermodynamic Properties of Aqueous Lithium Chloride Solutions. An Evaluation of the Gas Current Method for the Determination of the Thermodynamic Proper-ties of Aqueous Salt Solutions.

Cited by 33 publications

References 5 publications

Properties of aqueous solutions of lithium and calcium chlorides: formulations for use in air conditioning equipment design

Properties of aqueous solutions of lithium and calcium chlorides: formulations for use in air conditioning equipment design

Sorbent Properties of Halide-Free Ionic Liquids for Water and CO2 Perfusion

Analytical Study of a Heat Recovery/Desiccant Cooling System under Tunisian Climatic Conditions

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Sorbent Properties of Halide-Free Ionic Liquids for Water and CO₂ Perfusion