Thermodynamic Properties of Carbon Disulfide

O'Brien, L. J.; Alford, W. J.

doi:10.1021/ie50494a053

Search citation statements

Order By: Relevance

Paper Sections

Select...

Development Of the Equation Of State1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1958

2007

Publication Types

Select...

Other5

Article2

Relationship

Self Cite0

Independent7

Authors

Journals

Cited by 21 publications

(2 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…(reduced a'b' equation) (27) where wi{t) = kot~l + (0 -ko)t~2 (28) u>i(t) = 7s(lkoa + L60 -1)p + 0(0 -3)p2J h = 5.5 (31) Region II. High Density Gas.…”

Section: Development Of the Equation Of Statementioning

confidence: 99%

Generalized Equation of State for Gases and Liquids

Hirschfelder¹,

Buehler²,

McGee³

et al. 1958

Ind. Eng. Chem.

View full text Add to dashboard Cite

“…(reduced a'b' equation) (27) where wi{t) = kot~l + (0 -ko)t~2 (28) u>i(t) = 7s(lkoa + L60 -1)p + 0(0 -3)p2J h = 5.5 (31) Region II. High Density Gas.…”

Section: Development Of the Equation Of Statementioning

confidence: 99%

Generalized Equation of State for Gases and Liquids

Hirschfelder¹,

Buehler²,

McGee³

et al. 1958

Ind. Eng. Chem.

View full text Add to dashboard Cite

“…An excellent thermodynamic analysis of both the methane and charcoal routes is given (7) and, for the methane route, thermodynamic and kinetic data are available (2,8) as well as kinetic data for plant design (1,3). Thermodynamic properties of sulfur (11), carbon disulfide (5), and hydrogen sulfide (10) are tabulated in the literature.…”

mentioning

confidence: 99%

Carbon Disulfide

Haines¹

1963

Ind. Eng. Chem.

View full text Add to dashboard Cite

Carbon Disulfide

Smith¹,

Timmerman²

2000

Kirk-Othmer Encyclopedia of Chemical Technology

View full text Add to dashboard Cite

Carbon disulfide, CS 2 , is a highly volatile, flammable, clear, colorless, dense liquid that has many useful chemical and physical properties. An industrially important chemical for over one hundred years, most carbon disulfide is now produced by reaction of hydrocarbon gas with sulfur in a process developed in the 1950s, although many small capacity plants still employ a retort or electric furnace route based on wood charcoal and sulfur. Modern plants achieve a 99.99% pure carbon disulfide product by means of fractional distillation. Over 75% of the estimated one million tons of carbon disulfide produced worldwide in 1991 went into manufacturing viscose rayon and cellophane film. Carbon disulfide is also used in manufacturing numerous organic sulfur compounds for a variety of applications including rubber vulcanization accelerators, flotation chemicals, pharmaceutical intermediates, fungicides, and insecticides. The carbon disulfide process route to carbon tetrachloride was discontinued in the United States during 1991 because of environment pressures on the end product. Carbon disulfide is very toxic, and the U.S. Government limits the 8‐h time‐weighted average exposure to 4 ppm maximum (12 mg/m 3 ) in air. Health and environmental concerns related to carbon disulfide have curtailed some uses, such as in grain fumigants and solvents. Special precautions must be exercised in handling carbon disulfide because of its toxicity, high volatility, wide flammability range, and low ignition temperature.

show abstract

Thermodynamic Properties of Carbon Disulfide

Cited by 21 publications

References 0 publications

Generalized Equation of State for Gases and Liquids

Generalized Equation of State for Gases and Liquids

Carbon Disulfide

Carbon Disulfide

Contact Info

Product

Resources

About