Thermodynamic Properties of the Liquid Ternary System Bismuth—Cadmium—Tin

Thermodynamic properties of liquid cadmium-bismuth-lead-tin alloys

“…will be discussed more fully in the next section., the measurements on the binary cadmium alloys concurred with other investigations (3,4). …”

“…The 18 coefficients of an arbitrarily truncated equation (4) were evaluated by multiple linear regression for G~d at 500°C. The input data for the regression included: the measurements of Elliott and Chipman (3) for each binary subsystem (Figure 10), the measurements of Elliott and Chipman (11) for the ternary alloys of cadmium-bismuthlead and cadmium-lead-tin (Figure 13), the measurements of Mellgren (4) for ternary alloys of cadmium, bismuth and tin (Figure 14), and the present experimental measurements for 38 quaternary alloys ( Figure 15).…”

“…The 12 binary alloys involving cadmium were studied to permit comparison with the measurements of Elliott and Chipman (3) and Mellgren (4). Although they are not the only investigators to examine these binary cadmium alloys (5,6,7,8), they are the only authors who in addition report on ternary alloys pertinent to this investiga tion.…”

A comparison of the molecular interaction volume model with the subregular solution model in multicomponent liquid alloys

“…In order to contrast MIVM to SRSM in multicomponent liquid alloys, the activites of components of the ternary liquid alloys Cd-Bi-Pb, [21] Cd-Bi-Sn, Bi-Sn-Cd, Sn-Bi-Cd, [22] and Cd-Pb-Sn [23] at 773 K, the quaternary liquid alloys Cd-Bi-Pb-Sn [24] at 773 K, Zn-Sn-Cd-Pb [25] at 877 K, and ZnSn-Cd-Bi [26] at 877 K, and the quinary liquid alloys Zn-BiCd-Pb-Sn [27] at 877 K have been chosen because these data are well known to be reliable. In order to determine the required binary parameters A ij , A ji , B ji , and B ij , some parameters of pure metals and the infinite dilute thermodynamic properties of binary liquid alloys must be found for the models, as shown in Tables I through III, respectively.…”

“…In order to determine the required binary parameters A ij , A ji , B ji , and B ij , some parameters of pure metals and the infinite dilute thermodynamic properties of binary liquid alloys must be found for the models, as shown in Tables I through III, respectively. [21] and the Cd-Bi-Sn [22] liquid alloys at 773 K and the experimental data [22] [15] and SRSM with the experimental data [24] of activity of component Cd in the liquid alloys Cd-Bi-Pb-Sn at 773 K; solid line: a 1,pre ϭ a 1,exp Fig. 4-Comparison of the predicted values of MIVM [15] and SRSM with the experimental data [25] of activity of component Zn in the liquid alloys Zn-Sn-Cd-Bi at 877 K; solid line: a 1,pre ϭ a 1,exp Substituting the corresponding A ij and A ji , and B ji and B ij , into Eqs.…”