Thermodynamic Study of Oxygen in Liquid Copper

Thermodynamic description of the CuO system

“…Fig. 4 plots the liquid miscibility gap region with experimental data from Taskinen [9], Kuxman and Kurre [10], Kayahara et al [11], Gerlach et al [12], Kemori et al [13] and Sadat-Darbandi [14].…”

“…7 the stability diagram with 10,000/T versus log P O 2 is plotted. Experimental data from Taskinen [8,9], Kayahara et al [11], Kemori et al [13], Sadat-Darbandi [14], Osterwald [23], Oishi et al [22] and Moser and Fitzer [24] are included. The agreement between calculated and experimental values is good.…”

Thermodynamic assessment of the ternary systems Ga–Mg–O, Ga–Ni–O, Mg–Ni–O and extrapolation to the Ga–Mg–Ni–O phase diagram

“…Kemori et al [36] employed the same technique to determine the chemical potential of oxygen in solid and liquid nickel equilibrated with both NiO and NiGa 2 O 4 and reported the oxygen content in liquid nickel in equilibrium with both compounds. The enthalpy of formation of the stoichiometric NiGa 2 O 4 from NiO and ␤-Ga 2 O 3 ( f H = −3.4 ± 1.2 kJ mol −1 ) has been measured by high temperature solution calorimetry [2].…”

Effect of Oxygen on the Evaporation Rate of Lead from Liquid Copper under Reduced Pressure.

“…(5) and (6) gives the rate constant of free evaporation at higher oxygen content. In the present work, K O Cu was calculated from the surface tension of liquid Cu-O alloy as a function of P O 2 reported by Gallois and Lupis 19) and Gibbs free energy change of oxygen dissolution into liquid copper after Kemori et al,20) which was used to convert the oxygen partial pressure to the activity of oxygen in liquid copper with Eq. (8) and k e(Pb in Cu) are also shown in Fig.…”