Thermodynamische Untersuchungen an binären flüssigen Legierungen des Tellurs mit Gallium, Indium und Thallium / Thermodynamic Investigations on the Binary Liquid Alloys of Tellurium with Gallium, Indium and Thallium

The present study was carried out in order to find out a rule controlling the heat of mixing of liquid alloys.The bonding-parameter B of elements was evaluated based on the rigid rule on alloying. Values of the heat of mixing of total 138 alloy systems were regulated with success by values of the paramthe two kinds of parabolic and linear forms. It was thus made clear theoretically that the parameter B had the covalent and metallic characters.

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Activity Measurements of Liquid Ga–Te and Ga–Sb Alloys by EMF Method with Solid Electrolyte

Katayama

Nakayama

Nakaï

et al. 1987

Trans. JIM

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of galvanic cells with the solid electrolyte (ZrO2+CaO) was measured to determine the activities of gallium at high temperatures in the whole composition range for liquid Ga-Te and Ga-Sb alloys, and some thermodynamic functions were derived from the results. The cells used were as follows:The activities of gallium in liquid Ga-Te alloys at 1123 K showed large negative deviations from Raoult's law on the Te-rich side, and increased remarkably in the middle concentration range from negative to positive deviations from ideality. The activities of gallium in liquid Ga-Sb alloys at 1073 K showed moderate negative deviations from the ideality in the whole composition range. These data are compared with published data.

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Thermodynamische Untersuchungen an binären flüssigen Legierungen des Tellurs mit Gallium, Indium und Thallium / Thermodynamic Investigations on the Binary Liquid Alloys of Tellurium with Gallium, Indium and Thallium

Cited by 3 publications

References 0 publications

Thermodynamic assessment of the Ga–Se–Te system

Thermodynamic assessment of the Ga–Se–Te system

Quantitative Analysis on the Heat of Mixing of Liquid Alloys by Employing New Parameters

Activity Measurements of Liquid Ga–Te and Ga–Sb Alloys by EMF Method with Solid Electrolyte

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Thermodynamische Untersuchungen an binären flüssigen Legierungen des Tellurs mit Gallium, Indium und Thallium / Thermodynamic Investigations on the Binary Liquid Alloys of Tellurium with Gallium, Indium and Thallium

Cited by 3 publications

References 0 publications

Thermodynamic assessment of the Ga–Se–Te system

Thermodynamic assessment of the Ga–Se–Te system

Quantitative Analysis on the Heat of Mixing of Liquid Alloys by Employing New Parameters

Activity Measurements of Liquid Ga&ndash;Te and Ga&ndash;Sb Alloys by EMF Method with Solid Electrolyte

Contact Info

Product

Resources

About

Activity Measurements of Liquid Ga–Te and Ga–Sb Alloys by EMF Method with Solid Electrolyte