Thermogalvanic and local field effects in SiO2&lt;SmCl3&gt; structure

Grygorchak, I. I.; Całus, Dariusz; Pidluzhna, Anna; Ivashchyshyn, Fedir; Hryhorchak, O. I.; Chabecki, Piotr; Shvets, R. Ya.

doi:10.1007/s13204-020-01447-2

Cited by 12 publications

(9 citation statements)

References 19 publications

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“…The construction of clathrates with a hierarchical structure of supramolecular subhosthostguest ensembles enables the formation of inorganic/organic structures with the desired functional hybridity. For instance, in the clathrates that we recently synthesized at ambient temperature and weak magnetic fields, the colossal magnetoresistivity and magnetocapacitance effects [13,14], negative capacitance phenomenon and the possibility of accumulating electrical energy at the quantum level [15,16] were detected. Quantum mechanisms will allow to accumulate electricity of much higher density, which is predicted [17,18] to give impetus to the significant development of renewable energy systems.…”

Section: Introductionmentioning

confidence: 99%

GaSe(β-CD(J2)) Architecture Supramolecular Clathrate: Properties and Application

Maksymych¹,

Całus²,

Shvets³

et al. 2022

J. Nano- Electron. Phys.

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Modern nanotechnologies are designed to create functionally hybrid inorganic/organic materials with extraordinary properties. Great interest in this direction was gained by clathrates -inclusion compounds built on the hostguest principle. Applying intercalation techniques, the supramolecular structures thus formed can be ordered in a certain way using inorganic matrices, forming clathrates of subhost

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Section: Introductionmentioning

confidence: 99%

GaSe(β-CD(J2)) Architecture Supramolecular Clathrate: Properties and Application

Maksymych¹,

Całus²,

Shvets³

et al. 2022

J. Nano- Electron. Phys.

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“…For example, in the intercalation-formed clathrate GaSe<CS(NH 2 ) 2 <SmCl 3 >> the principle possibility of accumulation of electric energy at the quantum level was realized and the effect of "spin-battery" was fixed [5]. The encapsulation method was used to create clathrate МСМ-41<SmCl 3 > in which the occurrence of the effect of thermal EMF was recorded [6,7]. Thus, the goal of this work is to develop the scientific basis for the formation of intercalate heterophase structures with different nano-limited geometry, composition and level of hierarchy of architecture, aimed at the conversion and accumulation of electrical energy at the quantum level.…”

Section: Introductionmentioning

confidence: 99%

Quantum accumulation of electrical energy at interfacial boundaries in heterophase inorganic / organic clathrates

Maksymych¹,

Shvets²,

Ivashchyshyn³

2022

CPEE

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The work is devoted to the current problem of finding new ways and mechanisms of high-density electric energy accumulation. As a result of the conducted researches the system which allows to accumulate an electric charge at the expense of quantum effects and the phenomena without use of chemical reactions is offered. The basic idea was to form a material with a colossal area of the inner active surface with a sharply anisotropic chemical bonding character. Accordingly, the main goal was to create and study electrode materials based on intercalant heterophase structures with different types of hierarchy, capable of storing electrical energy at the quantum level. Based on the results of impedance spectroscopy, it was found that the obtained clathrate structures are promising for use as a cavitand electrode in a quantum battery, and, most importantly, can significantly increase its capacity

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“…A significant progress in QDs synthesis and application in photovoltaics has been attained in the field of II-VI semiconductors (Cd-containing in particular) (Su et al 2016;Rogach et al 2008;Zeng et al 2008;Barak et al 2018), especially recently because of energy crisis and intensive search for novel materials for all branches of energy saving technologies (Jasiński et al 2021;Grygorchak et al 2020;Ivashchyshyn et al 2021). However, the common inclusion of cadmium has rendered concerns about toxicity and cancer (Brunetti et al 2013;McKittrick and Shea-Rohwer 2014).…”

Section: Introductionmentioning

confidence: 99%

InP/ZnS quantum dots synthesis and photovoltaic application

et al. 2022

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In the present paper hybrid core–shell InP/ZnS quantum dots were prepared by the one pot synthesis method which does not require additional component injections and which complies more with cost requirements. The synthesized quantum dots were characterized by X-ray diffraction and optical spectroscopy methods. The applicability of the synthesized InP/ZnS core–shell particles in inverted solar cells fabricated with a step-by-step procedure which combines thermal vacuum deposition and spin-coating techniques was investigated. The resulting efficiency of the fabricated inverted solar cell is comparable to that of quantum-dot sensitized TiO2 based solar cells. Therefore, hybrid core–shell InP/ZnS particles can be considered as multifunctional light-harvesting materials useful for implementation in different types of photovoltaic devices, such as quantum dot sensitized solar cells and inverted solar cells.

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Thermogalvanic and local field effects in SiO2<SmCl3> structure

Cited by 12 publications

References 19 publications

GaSe(β-CD(J2)) Architecture Supramolecular Clathrate: Properties and Application

GaSe(β-CD(J2)) Architecture Supramolecular Clathrate: Properties and Application

Quantum accumulation of electrical energy at interfacial boundaries in heterophase inorganic / organic clathrates

InP/ZnS quantum dots synthesis and photovoltaic application

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