Abstract-We investigated thermoluminescence of silicates that are of interest in the interstellar and circumstellar medium after irradiation by y-rays and fast neutrons. The silicates are forsterite, orthoenstatite, olivine, quartz, and crystalline silicon. The irradiated enstatite shows weak and broad peaks at 545 and 760 nm. In contrast, irradiated bulk and powder samples offorsterite show strong and broad peaks at 640-660 nm. Although thermoluminescence of bulk forsterite is very similar to the extended red emission (ERE) of the Red Rectangle nebula, irradiated powdered forsterite did not reveal any sharp emission features over the broad band. Further, we investigated the possibility of thermoluminescence of crystalline silicon and found that luminescence scarcely appears. It is emphasized that the prominent carrier of ERE is forsterite and fused quartz.