Thermophysical properties of the binary mixtures (1,8-cineole+1-alkanol) at T=(298.15 and 313.15)K and at atmospheric pressure

Molar heat capacities of the mixture {1,8-cineole + ethanol} at several temperatures and atmospheric pressure

“…The maxima in excess heat capacity are placed at x 1 = 0.6 as also occurred for the excess enthalpies [2]. For mixtures (1-alkanol + alkane) this deviation has been attributed [30] to the fact that the structure of the alkanol is not completely broken during the mixing process.…”

“…Among these, the mixture of 1,8-cineole (1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octane) with alkanols has been the subject of an ample investigation in our research group, including properties such as excess molar enthalpy [2], density at low and high pressure [2][3][4] and (vapor +liquid) equilibrium [5,6]. 1,8-Cineole or eucalyptol, a monoterpenoid, is the main component of the volatile oils obtained from several plants and has many applications in the fields of flavour and fragrances, pharmacy.…”

Application of ERAS-model and Prigogine–Flory–Patterson theory to excess molar volumes for ternary mixtures of (2-chlorobutane+butylacetate+isobutanol) at T=298.15K

“…The specific interactions of alkyl acetate with alcohols can be visualized due to presence of ion pair of electrons on the oxygen atom of alkyl acetate on account of which it can act as a strong proton-acceptor from the alkanol. Further these system are also an ideal choice to examine ideal associated solution models with Flory's interaction term to predict and analyze theoretically the excess molar volume [14][15][16][17].…”

Analysis of thermophysical properties of binary systems containing ethyl acetate and 1-propanol or 1-butanol

“…The lines are a guide to the eye. [44], () [45], () [46], () [47], () [48], () [49], () [50], () [51], () [52], () [53], () [54], () [55], () [56], () [57], () [58], () [59], () [60], () [61], () [62], () [63], () [64], () [65], () [66], () [67], () [68], () [69], () [70], () [71], () [72], () [73], () [74], () [75], () [76], () [77], () [78], () [79], () [80], () [81], () [82], () [83], () [84], () [85], () [86], () [87], () [88], () [89], () [90], () [91], () [92]...…”