Achieving fibers that change color with temperature may
be promising
for applications such as sensors and smart wearable textiles (woven
and nonwoven). In this study, temperature-responsive cholesteryl ester
liquid crystal formulations were blended with polycaprolactone or
polystyrene using chloroform as a solvent for electrospinning to achieve
thermochromic nonwoven products. Using polystyrene, beaded fibers
were achieved and the thermochromic behavior was only observed under
polarized light microscopy. To achieve fibers with visible thermochromic
behavior observed by a video camera or smart phone, polycaprolactone
was used as a carrier polymer. The comparison between polystyrene
and polycaprolactone provides insight into polymer/solvent selection
achieving responsive materials via blend processing. High loadings
of liquid crystal were achieved with polycaprolactone, blends of 10
wt % polycaprolactone with 15 wt % liquid crystal formed fibers (fiber
contained 60 wt % liquid crystal). Colored fibers could be achieved
by varying the formulation of the liquid crystal. For example, liquid
crystal formulations that were green at ambient conditions resulted
in fibers that were green at ambient conditions (22 °C). Nonwoven
fibers with dynamic color with temperature were also demonstrated.
For example, liquid crystal formulations were colorless at ambient
conditions and underwent a reversible color change from red to blue
when heated and cooled between 32 and 37 °C. When incorporated
into fibers, the fiber mats changed from white at ambient conditions
to red at 32 °C to blue at 37 °C. The color change was reversible
over multiple cycles.