Thetris(2-nitroso-1-naphtholato)ferrate(II) ion

Vibrational analysis of 1-methyl-pyridinium-2-aldoxime and 1-methyl-pyridinium-4-aldoxime cations

“…Since the question regarding the morphology and active conformation of a solid simple mono-pyridinium aldoximes is still open [7], and since at physiological pH (7.4) oxime group exists both in protonated and in deprotonated forms [6], one could gain much information by studying the pyridinium aldoxime solution vibrational spectra. Therefore the first step would be to assign the vibrational bands of the protonated conformers appearing in crystals.…”

“…Stability and reactivity (nucleophilicity and reactivation ability) of pyridinium aldoximes is closely related to their morphology, configuration and conformation, which also determines the acidity of aldoxime group. The configuration of aldoxime group and consequently its acidity and nucleophilicity in such compounds are known to vary with temperature or upon UV irradiation [4][5][6].…”

Thermal, X-Ray Diffraction, Spectral and Antimicrobial Activity of Bivalent Metal (Zn, Cd, Hg, Pb and Ag) Chelates Of 1, 2 Naphthoquinone – 2, Oxime,

“…The authors concluded that the color of the quinone oxime complexes was not related to a quinone oxime or nitrosophenol structure (1). The Fe (III) complex of 1-2-naphthoquinone-2, oxime have been reported and its IR spectra were explained along with electronic spectra (2). The stability constants of the metal chelates of 1-2-naphthoquinone-2, oxime with Mn, Co, Ni, Cu, Zn, VO (II) and UO2 (II) were determined.…”