Abstract. Pesticides are contaminants of priority concern that
continue to present a significant risk to drinking water quality. While
pollution mitigation in catchment systems is considered a cost-effective
alternative to costly drinking water treatment, the effectiveness of
pollution mitigation measures is uncertain and needs to be able to consider
local biophysical, agronomic, and social aspects. We developed a
probabilistic decision support tool (DST) based on spatial Bayesian belief
networks (BBNs) that simulates inherent pesticide leaching risk to ground-
and surface water quality to inform field-level pesticide mitigation
strategies in a small (3.1 km2) drinking water catchment with limited
observational data. The DST accounts for the spatial heterogeneity in soil
properties, topographic connectivity, and agronomic practices; the temporal
variability of climatic and hydrological processes; and uncertainties
related to pesticide properties and the effectiveness of management
interventions. The rate of pesticide loss via overland flow and leaching to
groundwater and the resulting risk of exceeding a regulatory threshold for
drinking water was simulated for five active ingredients. Risk factors
included climate and hydrology (e.g. temperature, rainfall, evapotranspiration,
and overland and subsurface flow), soil properties (e.g. texture, organic matter
content, and hydrological properties), topography (e.g. slope and distance to surface
water/depth to groundwater), land cover and agronomic practices, and pesticide
properties and usage. The effectiveness of mitigation measures such as the
delayed timing of pesticide application; a 10 %, 25 %, or 50 % reduction
in the application rate; field buffers; and the presence/absence of soil pan on risk
reduction were evaluated. Sensitivity analysis identified the month of
application, the land use, the presence of buffers, the field slope, and the distance as the
most important risk factors, alongside several additional influential
variables. The pesticide pollution risk from surface water runoff showed clear
spatial variability across the study catchment, whereas the groundwater leaching
risk was uniformly low, with the exception of prosulfocarb. Combined
interventions of a 50 % reduced pesticide application rate, management of the
plough pan, delayed application timing, and field buffer installation notably
reduced the probability of a high risk of overland runoff and groundwater
leaching, with individual measures having a smaller impact. The graphical
nature of BBNs facilitated interactive model development and evaluation
with stakeholders to build model credibility, while the ability to integrate
diverse data sources allowed a dynamic field-scale assessment of “critical
source areas” of pesticide pollution in time and space in a data-scarce
catchment, with explicit representation of uncertainties.